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Femtosecond reaction dynamics in the gas-to-liquid transition region: Observation of a three-phase density dependence

Liu, Qianli and Wan, Chaozhi and Zewail, Ahmed H. (1996) Femtosecond reaction dynamics in the gas-to-liquid transition region: Observation of a three-phase density dependence. Journal of Chemical Physics, 105 (12). pp. 5294-5297. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:20160824-143936307

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Abstract

We report the observation of a striking density dependence in the coherencedynamics of an elementary reaction, solute iodine in solvent rare gases (density from 0 to 50 mol/l). With the help of MD simulations, the time scales of slow and fast solvent‐force fluctuations are resolved and the underlying mechanism is revealed.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1063/1.472371DOIArticle
http://scitation.aip.org/content/aip/journal/jcp/105/12/10.1063/1.472371PublisherArticle
Additional Information:© 1996 American Institute of Physics. Received 26 June 1996; accepted 16 July 1996. Most of the simulation works were performed on the Delta parallel supercomputer located at Caltech. The authors are grateful to Professor Vincent McKoy for providing the access to the supercomputer. We thank Mr. Chris Hyland, Dr. Cristoph Lienau, and Mr. Manish Gupta for their help in the initial phase of the work and Professor David Chandler for helpful discussions.
Record Number:CaltechAUTHORS:20160824-143936307
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20160824-143936307
Official Citation:Femtosecond reaction dynamics in the gas‐to‐liquid transition region: Observation of a three‐phase density dependence Liu, Qianli and Wan, Chaozhi and Zewail, Ahmed H., The Journal of Chemical Physics, 105, 5294-5297 (1996), DOI:http://dx.doi.org/10.1063/1.472371
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:69906
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:26 Aug 2016 17:56
Last Modified:26 Aug 2016 17:56

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