Wan, Choazhi and Gupta, Manish and Zewail, Ahmed H. (1996) Femtochemistry of ICN in liquids: dynamics of dissociation, recombination and abstraction. Chemical Physics Letters, 256 (3). pp. 279-287. ISSN 0009-2614. doi:10.1016/0009-2614(96)00443-5. https://resolver.caltech.edu/CaltechAUTHORS:20160824-143938433
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Abstract
The femtosecond reaction dynamics of ICN in the liquids CHCl_3, CH_2Cl_2, and CDCl_3 are reported. As in gas phase studies, we probed the dynamics of bond breakage and rotational alignment, but not in the presence of the solvent structure. Furthermore, we observed the subsequent process of solvent-induced atom-diatom recombination and examined its role in the overall mechanism of hydrogen (and chlorine) abstraction reaction. The elementary dynamics in these liquid solutions, and for two different states of the reaction (CN + I and CN + I∗), are compared with molecular dynamics simulations, which provide a remarkably good microscopic picture of the different femtochemical steps.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1996 Elsevier B.V. Received 2 April 1996. This work was supported by a grant from the National Science Foundation. We wish to thank Professor B.V. McKoy for helpful comments and thorough reading of the manuscript. | |||||||||
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| Issue or Number: | 3 | |||||||||
| DOI: | 10.1016/0009-2614(96)00443-5 | |||||||||
| Record Number: | CaltechAUTHORS:20160824-143938433 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160824-143938433 | |||||||||
| Official Citation: | Choazhi Wan, Manish Gupta, Ahmed H. Zewail, Femtochemistry of ICN in liquids: dynamics of dissociation, recombination and abstraction, Chemical Physics Letters, Volume 256, Issue 3, 28 June 1996, Pages 279-287, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(96)00443-5. (http://www.sciencedirect.com/science/article/pii/0009261496004435) | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 69913 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 26 Aug 2016 17:10 | |||||||||
| Last Modified: | 11 Nov 2021 04:21 |
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