Kim, Sang Kyu and Guo, Ju and Baskin, J. Spencer and Zewail, Ahmed H. (1996) Femtosecond Chemically Activated Reactions: Concept of Nonstatistical Activation at High Thermal Energies. Journal of Physical Chemistry, 100 (22). pp. 9202-9205. ISSN 0022-3654. doi:10.1021/jp961066c. https://resolver.caltech.edu/CaltechAUTHORS:20160825-074651641
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Abstract
Femtosecond chemical activation of reactions at very high thermal energies, much above the bond energy, is developed in this report. We address the concept of nonstatistical dynamics at such high energies. The approach offers a new direction for probing the dynamics of reactions in their ground state with unique activation, collision-free, and temporally and spatially defined.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1996 American Chemical Society. Received: April 8, 1996. Publication Date (Web): May 30, 1996. Abstract published in Advance ACS Abstracts, May 15, 1996. This research was supported by the National Science Foundation and by a grant from the Air Force Office of Scientific Research. We thank Mr. Obadiah Manley for his help with the RRKM calculations and Professors R. Marcus and J. Berson for many useful discussions. | |||||||||
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| Issue or Number: | 22 | |||||||||
| DOI: | 10.1021/jp961066c | |||||||||
| Record Number: | CaltechAUTHORS:20160825-074651641 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160825-074651641 | |||||||||
| Official Citation: | Femtosecond Chemically Activated Reactions: Concept of Nonstatistical Activation at High Thermal Energies Sang Kyu Kim, Ju Guo, J. Spencer Baskin, and Ahmed H. Zewail The Journal of Physical Chemistry 1996 100 (22), 9202-9205 DOI: 10.1021/jp961066c | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 69916 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 26 Aug 2016 16:03 | |||||||||
| Last Modified: | 11 Nov 2021 04:21 |
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