Kim, Sang Kyu and Pedersen, Soren and Zewail, Ahmed H. (1995) Femtochemistry of organometallics: dynamics of metal-metal and metal-ligand bond cleavage in M_2(CO)_(10). Chemical Physics Letters, 233 (5-6). pp. 500-508. ISSN 0009-2614. doi:10.1016/0009-2614(95)00050-E. https://resolver.caltech.edu/CaltechAUTHORS:20160825-105754120
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Abstract
We report femtochemical studies of the organometallic dimetal decacarbonyl. By the use of mass spectrometry, we obtain the temporal dynamics in the channels for metal-metal and metal-ligand bond cleavage. The time scale observed for cleavage and for structural bridging indicates the nature of the repulsion along the two reaction coordinates and the interplay between the bond order and the femtosecond dynamics.
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| Additional Information: | © 1995 Elsevier Science B.V. Received 30 December 1994. This work was supported by a grant from the National Science Foundation. We wish to thank Professor J. Manz for stimulating and helpful correspondence, and Professor S. Ruhman for communicating his work. | |||||||||
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| Issue or Number: | 5-6 | |||||||||
| DOI: | 10.1016/0009-2614(95)00050-E | |||||||||
| Record Number: | CaltechAUTHORS:20160825-105754120 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160825-105754120 | |||||||||
| Official Citation: | Sang Kyu Kim, Soren Pedersen, Ahmed H. Zewail, Femtochemistry of organometallics: dynamics of metal-metal and metal-ligand bond cleavage in M2(CO)10, Chemical Physics Letters, Volume 233, Issue 5, 1995, Pages 500-508, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(95)00050-E. (http://www.sciencedirect.com/science/article/pii/000926149500050E) | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 69934 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 26 Aug 2016 15:29 | |||||||||
| Last Modified: | 11 Nov 2021 04:22 |
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