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Femtochemistry at high pressures. Solvent effect in the gas-to-liquid transition region

Lienau, Ch. and Zewail, A. H. (1994) Femtochemistry at high pressures. Solvent effect in the gas-to-liquid transition region. Chemical Physics Letters, 222 (3). pp. 224-232. ISSN 0009-2614. https://resolver.caltech.edu/CaltechAUTHORS:20160825-105755758

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Abstract

We report new studies on the effect of solvent on the femtosecond dynamics of the dissociation and recombination of iodine in the gas-to-liquid transition region. The pressure of the solvent (helium, neon, argon and krypton) spans the range from 0 to 2500 bar, corresponding to solvent densities from the ideal gas-phase limit to the liquid-like fluid regime. The reactive cross section and the dynamics of the collision of the fragments with the solvent and with each other are discussed in relation to the solvent polarizability and the structure of the solvent cage.


Item Type:Article
Related URLs:
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http://dx.doi.org/10.1016/0009-2614(94)00384-XDOIArticle
http://www.sciencedirect.com/science/article/pii/000926149400384XPublisherArticle
Additional Information:© 1994 Elsevier Science B.V. Received 22 March 1994. This work was supported by the National Science Foundation. Ch L gratefully acknowledges a postdoctoral fellowship by the Deutsche Forschungsgemeinschaft. We wish to thank Mr. Christopher Hyland for his help and discussions throughout this work.
Funders:
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NSFUNSPECIFIED
Deutsche Forschungsgemeinschaft (DFG)UNSPECIFIED
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Other Numbering System NameOther Numbering System ID
Arthur Amos Noyes Laboratory of Chemical Physics8933
Issue or Number:3
Record Number:CaltechAUTHORS:20160825-105755758
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160825-105755758
Official Citation:Ch. Lienau, A.H. Zewail, Femtochemistry at high pressures. Solvent effect in the gas-to-liquid transition region, Chemical Physics Letters, Volume 222, Issue 3, 1994, Pages 224-232, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(94)00384-X. (http://www.sciencedirect.com/science/article/pii/000926149400384X)
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ID Code:69940
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:26 Aug 2016 15:27
Last Modified:03 Oct 2019 10:26

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