Potter, E. D. and Liu, Q. and Zewail, A. H. (1992) Femtosecond reaction dynamics in macroclusters. Effect of solvation on wave-packet motion. Chemical Physics Letters, 200 (6). pp. 605-614. ISSN 0009-2614. doi:10.1016/0009-2614(92)80098-V. https://resolver.caltech.edu/CaltechAUTHORS:20160829-150314551
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20160829-150314551
Abstract
The dynamics of I_2 dissociation and recombination (caging) in a macrocluster are reported, covering the femtosecond to picosecond time domain. Both the exit-channel and recombination dynamics are observed and related to solute—solvent interactions. The dissociation involves bond breakage on bound/repulsive potentials with concomitant evaporation of the solvent shell. The caging is accompanied by relaxation of the system and/or diffusion of the free iodine atoms prior to reforming the I_2 bond. Molecular dynamics are used to compare with experiments.
| Item Type: | Article | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| |||||||||
| Additional Information: | © 1992 Elsevier Science Publishers B.V. Received 3 October 1992; in final form 16 October 1992. This work was supported by a grant from the National Science Foundation (DMR). | |||||||||
| Funders: |
| |||||||||
| Other Numbering System: |
| |||||||||
| Issue or Number: | 6 | |||||||||
| DOI: | 10.1016/0009-2614(92)80098-V | |||||||||
| Record Number: | CaltechAUTHORS:20160829-150314551 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160829-150314551 | |||||||||
| Official Citation: | E.D. Potter, Q. Liu, A.H. Zewail, Femtosecond reaction dynamics in macroclusters. Effect of solvation on wave-packet motion, Chemical Physics Letters, Volume 200, Issue 6, 25 December 1992, Pages 605-614, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(92)80098-V. (http://www.sciencedirect.com/science/article/pii/000926149280098V) | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 69996 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 31 Aug 2016 04:35 | |||||||||
| Last Modified: | 11 Nov 2021 04:22 |
Repository Staff Only: item control page
