Heikal, Ahmed and Bañares, Luis and Semmes, David H. and Zewail, Ahmed H. (1991) Real-time dynamics of vibrational predissociation in anthracene-Ar_n (n = 1, 2, 3). Chemical Physics, 156 (2). pp. 231-250. ISSN 0301-0104. doi:10.1016/0301-0104(91)80092-V. https://resolver.caltech.edu/CaltechAUTHORS:20160829-150316358
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Abstract
The vibrational predissociation of van der Waals complexes of anthracene-Ar_n (n = 1, 2, 3), isolated in a supersonic expansion, has been studied following excitation to single vibrational levels ( 12_0^1, 10_0^1 12_0^2 6_0^1) in S^1. Using picosecond t spectroscopy, the intramolecularvibrational-energy redistribution IVR and the vibrational predissociation (VP) dynamics are studied and related to the character ofthe mode and its energy. The IVR and VP rates are also discussed in relation to the cluster size.
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| Additional Information: | © 1991 Elsevier Science Publishers B.V. Received 13 May 1991. This work was supported by a grant from the National Science Foundation (DMR). | |||||||||
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| Issue or Number: | 2 | |||||||||
| DOI: | 10.1016/0301-0104(91)80092-V | |||||||||
| Record Number: | CaltechAUTHORS:20160829-150316358 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160829-150316358 | |||||||||
| Official Citation: | Ahmed Heikal, Luis Bañares, David H. Semmes, Ahmed H. Zewail, Real-time dynamics of vibrational predissociation in anthracene-Arn (n = 1, 2, 3), Chemical Physics, Volume 156, Issue 2, 1 October 1991, Pages 231-250, ISSN 0301-0104, http://dx.doi.org/10.1016/0301-0104(91)80092-V. (http://www.sciencedirect.com/science/article/pii/030101049180092V) | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 70002 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 31 Aug 2016 04:44 | |||||||||
| Last Modified: | 11 Nov 2021 04:23 |
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