Willberg, D. M. and Breen, J. J. and Gutmann, M. and Zewail, A. H. (1991) Rotational constants of vibrationally excited iodine from purely rotational coherence observed in pump-probe experiments. Journal of Physical Chemistry, 95 (19). pp. 7136-7138. ISSN 0022-3654. doi:10.1021/j100172a010. https://resolver.caltech.edu/CaltechAUTHORS:20160830-102557022
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Abstract
Pump-probe laser-induced fluorescence techniques are used to determine the rotational constants of vibrationally excited iodine, cooled by supersonic beam expansions. For comparison, it is shown that the results obtained from real time (purely rotational coherence) are in excellent agreement with literature values for the v' = 12-23 of the B state. Results for nascent I_2 (v' = 22), from the predissociation of I_2Ne (v' = 23), are also reported.
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| Additional Information: | © 1991 American Chemical Society. Received: July 12, 1991; In Final Form: August 8, 1991. This work was supported by a grant from the National Science Foundation. | |||||||||
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| Issue or Number: | 19 | |||||||||
| DOI: | 10.1021/j100172a010 | |||||||||
| Record Number: | CaltechAUTHORS:20160830-102557022 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160830-102557022 | |||||||||
| Official Citation: | Rotational constants of vibrationally excited iodine from purely rotational coherence observed in pump-probe experiments D. M. Willberg, J. J. Breen, M. Gutmann, and A. H. Zewail The Journal of Physical Chemistry 1991 95 (19), 7136-7138 DOI: 10.1021/j100172a010 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 70026 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 31 Aug 2016 04:07 | |||||||||
| Last Modified: | 11 Nov 2021 04:23 |
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