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Femtosecond temporal spectroscopy and direct inversion to the potential: Application to iodine

Gruebele, M. and Roberts, G. and Dantus, M. and Bowman, R. M. and Zewail, A. H. (1990) Femtosecond temporal spectroscopy and direct inversion to the potential: Application to iodine. Chemical Physics Letters, 166 (5-6). pp. 459-469. ISSN 0009-2614. https://resolver.caltech.edu/CaltechAUTHORS:20160831-091534221

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Abstract

The use of femtosecond lasers in probing molecular dynamics is usually thought to yield improved temporal resolution, at the expense of spectral information. Here, we report on the use of femtosecond temporal spectroscopy (FTS) to yield accurate spectral information (vibrational and rotational) and to invert directly to the potential energy curve. As an example, we present the FTS analysis, inversion to the potential, and confirmatory wave packet calculations for the B ^3Π_(0+u) state of molecular iodine.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0009-2614(90)87134-DDOIArticle
http://www.sciencedirect.com/science/article/pii/000926149087134DPublisherArticle
Additional Information:© 1990 Elsevier Science Publishers B.V. Received 19 January 1990. This work was supported by the National Science Foundation and the Air Force Office of Scientific Research. One of us (GR) thanks SERC for the award of a NATO Postdoctoral Fellowship.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
Science and Engineering Research Council (SERC)UNSPECIFIED
North Atlantic Treaty Organization (NATO)UNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Arthur Amos Noyes Laboratory of Chemical Physics8096
Issue or Number:5-6
Record Number:CaltechAUTHORS:20160831-091534221
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160831-091534221
Official Citation:M. Gruebele, G. Roberts, M. Dantus, R.M. Bowman, A.H. Zewail, Femtosecond temporal spectroscopy and direct inversion to the potential: Application to iodine, Chemical Physics Letters, Volume 166, Issues 5–6, 9 March 1990, Pages 459-469, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(90)87134-D. (http://www.sciencedirect.com/science/article/pii/000926149087134D)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:70060
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:31 Aug 2016 16:55
Last Modified:03 Oct 2019 10:27

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