Tinti, D. S. and Baskin, J. Spencer and Zewail, Ahmed H. (1989) Picosecond studies of jet-cooled chromyl chloride. Chemical Physics Letters, 155 (3). pp. 243-250. ISSN 0009-2614. doi:10.1016/0009-2614(89)85318-7. https://resolver.caltech.edu/CaltechAUTHORS:20160902-105851543
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20160902-105851543
Abstract
The dynamics of the ^1B_1 state of chromyl chloride, CrO_2Cl_2, are investigated via picosecond time-resolved measurements on a jet-cooled sample. Quasi-biexponential time evolution of fluorescence is observed for each of the nine single vibronic levels studied. A rapid, mode-dependent acceleration of the decay rates with excess vibrational energy is reported. The time dependence is described by a kinetic model and the non-radiative decay channels which may be responsible for the observed behavior are discussed.
| Item Type: | Article | ||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| ||||||||||||
| Additional Information: | © 1989 Elsevier Science Publishers B.V. Received 1 November 1988; in final form 9 December 1988. This research was supported by the Caltech Consortium in Chemistry and Chemical Engineering; founding members: E.I. du Pont de Nemours and Company, Inc., Eastman Kodak Company, Minnesota Mining and Manufacturing Company, and Shell Oil Company Foundation. We wish to thank the referee for useful comments. | ||||||||||||
| Funders: |
| ||||||||||||
| Other Numbering System: |
| ||||||||||||
| Issue or Number: | 3 | ||||||||||||
| DOI: | 10.1016/0009-2614(89)85318-7 | ||||||||||||
| Record Number: | CaltechAUTHORS:20160902-105851543 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160902-105851543 | ||||||||||||
| Official Citation: | D.S. Tinti, J.Spencer Baskin, Ahmed H. Zewail, Picosecond studies of jet-cooled chromyl chloride, Chemical Physics Letters, Volume 155, Issue 3, 3 March 1989, Pages 243-250, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(89)85318-7. (http://www.sciencedirect.com/science/article/pii/0009261489853187) | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 70151 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Ruth Sustaita | ||||||||||||
| Deposited On: | 02 Sep 2016 19:57 | ||||||||||||
| Last Modified: | 11 Nov 2021 04:25 |
Repository Staff Only: item control page
