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Femtosecond real-time probing of reactions. II. The dissociation reaction of ICN

Dantus, Marcos and Rosker, Mark J. and Zewail, Ahmed H. (1988) Femtosecond real-time probing of reactions. II. The dissociation reaction of ICN. Journal of Chemical Physics, 89 (10). pp. 6128-6140. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:20160902-131819394

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Abstract

Experimental results obtained for the dissociation reaction ICN^*→[I⋅⋅⋅CN]^(‡*)→I+CN using femtosecond transition‐state spectroscopy (FTS) are presented. The process of the I–CN bond breaking is clocked, and the transition states of the reaction are observed in real time. From the clocking experiments, a "dissociation" time of 205±30 fs was measured and was related to the length scale of the potential. The transition states live for only ∼50 fs or less, and from the observed transients we deduce some characteristics of the relevant potential energy surfaces (PES). These FTS experiments are discussed in relation to both classical and quantum mechanical models of the dynamical motion, including features of the femtosecondcoherence and alignment of fragments during recoil. The observations are related to the radial and angular properties of the PES.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1063/1.455428DOIArticle
http://scitation.aip.org/content/aip/journal/jcp/89/10/10.1063/1.455428PublisherArticle
Additional Information:© 1988 American Institute of Physics. Received 12 July 1988; accepted 11 August 1988. This work was supported by AFOSR (Grant No. 87-0071). Contribution No. 7814. We wish to thank the referee of this and the previous paper for a thorough and comprehensive review.
Funders:
Funding AgencyGrant Number
Air Force Office of Scientific Research (AFOSR)87-0071
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Arthur Amos Noyes Laboratory of Chemical Physics7814
Record Number:CaltechAUTHORS:20160902-131819394
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20160902-131819394
Official Citation:Femtosecond real‐time probing of reactions. II. The dissociation reaction of ICN Marcos Dantus, Mark J. Rosker and Ahmed H. Zewail J. Chem. Phys. 89, 6128 (1988); http://dx.doi.org/10.1063/1.455428
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:70157
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:06 Sep 2016 19:10
Last Modified:06 Sep 2016 19:10

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