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Femtosecond real-time dynamics of photofragment-trapping resonances on dissociative potential energy surfaces

Rosker, Mark J. and Rose, Todd S. and Zewail, Ahmed H. (1988) Femtosecond real-time dynamics of photofragment-trapping resonances on dissociative potential energy surfaces. Chemical Physics Letters, 146 (3-4). pp. 175-179. ISSN 0009-2614. http://resolver.caltech.edu/CaltechAUTHORS:20160906-090609878

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Abstract

The real-time dynamics of wave packet resonance (due to photofragment trapping) in the reaction of NaI is reported using femtosecond transition-state spectroscopy (FTS). The observed oscillation frequency and delay give the effective vibrational frequency of the trapping well and the probability of leaving the well, respectively. The energy dependence of the wave packet oscillation provides the shape of the quasi-bound potential well in NaI.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0009-2614(88)87426-8DOIArticle
http://www.sciencedirect.com/science/article/pii/0009261488874268PublisherArticle
Additional Information:© Elsevier Science Publishers B.V. Received 7 April 1988. This work was supported by the AFOSR (Grant No. 87-0071).
Funders:
Funding AgencyGrant Number
Air Force Office of Scientific Research (AFOSR)87-0071
Record Number:CaltechAUTHORS:20160906-090609878
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20160906-090609878
Official Citation:Mark J. Rosker, Todd S. Rose, Ahmed H. Zewail, Femtosecond real-time dynamics of photofragment-trapping resonances on dissociative potential energy surfaces, Chemical Physics Letters, Volume 146, Issues 3–4, 6 May 1988, Pages 175-179, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(88)87426-8. (http://www.sciencedirect.com/science/article/pii/0009261488874268)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:70161
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:06 Sep 2016 19:05
Last Modified:06 Sep 2016 19:05

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