Rosker, Mark J. and Rose, Todd S. and Zewail, Ahmed H. (1988) Femtosecond real-time dynamics of photofragment-trapping resonances on dissociative potential energy surfaces. Chemical Physics Letters, 146 (3-4). pp. 175-179. ISSN 0009-2614. http://resolver.caltech.edu/CaltechAUTHORS:20160906-090609878
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Abstract
The real-time dynamics of wave packet resonance (due to photofragment trapping) in the reaction of NaI is reported using femtosecond transition-state spectroscopy (FTS). The observed oscillation frequency and delay give the effective vibrational frequency of the trapping well and the probability of leaving the well, respectively. The energy dependence of the wave packet oscillation provides the shape of the quasi-bound potential well in NaI.
| Item Type: | Article | |||||||||
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| Additional Information: | © Elsevier Science Publishers B.V. Received 7 April 1988. This work was supported by the AFOSR (Grant No. 87-0071). | |||||||||
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| Record Number: | CaltechAUTHORS:20160906-090609878 | |||||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20160906-090609878 | |||||||||
| Official Citation: | Mark J. Rosker, Todd S. Rose, Ahmed H. Zewail, Femtosecond real-time dynamics of photofragment-trapping resonances on dissociative potential energy surfaces, Chemical Physics Letters, Volume 146, Issues 3–4, 6 May 1988, Pages 175-179, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(88)87426-8. (http://www.sciencedirect.com/science/article/pii/0009261488874268) | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 70161 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 06 Sep 2016 19:05 | |||||||||
| Last Modified: | 06 Sep 2016 19:05 |
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