Scherer, Norbert F. and Khundkar, Lutfur R. and Bernstein, Richard B. and Zewail, Ahmed H. (1987) Real-time picosecond clocking of the collision complex in a bimolecular reaction: The birth of OH from H+CO_2. Journal of Chemical Physics, 87 (2). pp. 1451-1453. ISSN 0021-9606. doi:10.1063/1.453280. https://resolver.caltech.edu/CaltechAUTHORS:20160906-090612033
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Abstract
Picosecond (and femtosecond) photofragment spectroscopy has recently provided time-resolved, state-to-state dynamics of molecular photofragmentation. The focus of these experiments was on unimolecular reactions, where two main issues are fundamental to the dynamics: the nature of the "half-collision" and the degree to which statistical theories account for the time evolution of product state distributions (PSDs).
| Item Type: | Article | |||||||||
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| Additional Information: | © 1987 American Institute of Physics. Received 13 April 1987; accepted 12 May 1987. Research supported by the National Science Foundation under Grant No. DMR-8521191. | |||||||||
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| Issue or Number: | 2 | |||||||||
| DOI: | 10.1063/1.453280 | |||||||||
| Record Number: | CaltechAUTHORS:20160906-090612033 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160906-090612033 | |||||||||
| Official Citation: | Real‐time picosecond clocking of the collision complex in a bimolecular reaction: The birth of OH from H+CO2 Scherer, Norbert F. and Khundkar, Lutfur R. and Bernstein, Richard B. and Zewail, Ahmed H., The Journal of Chemical Physics, 87, 1451-1453 (1987), DOI:http://dx.doi.org/10.1063/1.453280 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 70168 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 09 Sep 2016 18:29 | |||||||||
| Last Modified: | 11 Nov 2021 04:25 |
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