Aluthge, Dinesh C. and Sattler, Aaron and Al-Harthi, Mamdouh A. and Labinger, Jay A. and Bercaw, John E. (2016) Cosupported Tandem Catalysts for Production of Linear Low-Density Polyethylene from an Ethylene-Only Feed. ACS Catalysis, 6 (10). pp. 6581-6584. ISSN 2155-5435. doi:10.1021/acscatal.6b02370. https://resolver.caltech.edu/CaltechAUTHORS:20160912-085645255
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Abstract
Linear low-density polyethylene (LLDPE) is produced from an ethylene-only feed over a tandem catalyst system consisting of a phenoxy–imine titanium trimerization catalyst and a silylene-linked cyclopentadienyl/amido titanium polymerization catalyst cosupported on the same methylaluminoxane/silica particles. The level of 1-hexene incorporation can be controlled by varying the ethylene pressure.
Item Type: | Article | ||||||||||||
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Additional Information: | © 2016 American Chemical Society. Received: August 18, 2016; Revised: August 29, 2016. Publication Date (Web): August 31, 2016. This work was supported by a grant from King Fahd University of Petroleum and Minerals. The authors thank Prof. Julie Kornfield for helpful discussions, Dr. John Power and Albemarle Corporation for a generous gift of MAO. The authors declare no competing financial interest. | ||||||||||||
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Subject Keywords: | cosupported catalysts; ethylene trimerization; linear low-density polyethylene; olefin polymerization; tandem catalysis | ||||||||||||
Issue or Number: | 10 | ||||||||||||
DOI: | 10.1021/acscatal.6b02370 | ||||||||||||
Record Number: | CaltechAUTHORS:20160912-085645255 | ||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160912-085645255 | ||||||||||||
Official Citation: | Cosupported Tandem Catalysts for Production of Linear Low-Density Polyethylene from an Ethylene-Only Feed Dinesh C. Aluthge, Aaron Sattler, Mamdouh A. Al-Harthi, Jay A. Labinger, and John E. Bercaw ACS Catalysis 2016 6 (10), 6581-6584 DOI: 10.1021/acscatal.6b02370 | ||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
ID Code: | 70268 | ||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||
Deposited By: | Tony Diaz | ||||||||||||
Deposited On: | 12 Sep 2016 19:20 | ||||||||||||
Last Modified: | 11 Nov 2021 04:26 |
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