Agapie, Theodor (2016) Reactivity of metal complexes supported by ligands with functionalized pendant ar. In: 252nd American Chemical Society National Meeting & Exposition, 21-25 August 2016, Philadelphia, PA. https://resolver.caltech.edu/CaltechAUTHORS:20160913-082846175
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Abstract
Multidentate phosphines connected by terphenyl linkers have been employ multimetallic complexes. The central arene of the terphenyl unit acts as a labile variety of modes as a function of metal and oxidn. state. Addnl., this arene can to redox and H-transfer chem. Mo complexes with P-arene-P pincers show reductive coupling of two CO mols. demonstrating the ability of such ligands to s activation chem. Variants with catechol and hydroquinone moieties perform transfer chem. Mechanistic studies of reactions with O_2 show that second-sphere O_2 activation steps. The coordination chem. of these systems and reactivit discussed.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
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| Additional Information: | © 2016 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20160913-082846175 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160913-082846175 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 70290 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 29 Sep 2016 23:58 | ||||||
| Last Modified: | 03 Oct 2019 10:29 |
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