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Reactivity of metal complexes supported by ligands with functionalized pendant ar

Agapie, Theodor (2016) Reactivity of metal complexes supported by ligands with functionalized pendant ar. In: 252nd American Chemical Society National Meeting & Exposition, 21-25 August 2016, Philadelphia, PA.

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Multidentate phosphines connected by terphenyl linkers have been employ multimetallic complexes. The central arene of the terphenyl unit acts as a labile variety of modes as a function of metal and oxidn. state. Addnl., this arene can to redox and H-transfer chem. Mo complexes with P-arene-P pincers show reductive coupling of two CO mols. demonstrating the ability of such ligands to s activation chem. Variants with catechol and hydroquinone moieties perform transfer chem. Mechanistic studies of reactions with O_2 show that second-sphere O_2 activation steps. The coordination chem. of these systems and reactivit discussed.

Item Type:Conference or Workshop Item (Paper)
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Agapie, Theodor0000-0002-9692-7614
Additional Information:© 2016 American Chemical Society.
Record Number:CaltechAUTHORS:20160913-082846175
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:70290
Deposited By: Tony Diaz
Deposited On:29 Sep 2016 23:58
Last Modified:03 Oct 2019 10:29

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