Cannon, Jeff and Luo, Shaoxiong and Engle, Keary and Taylor, Buck and Houk, Kendall and Grubbs, Robert (2016) Z-selective cross metathesis with 3(E)-1,3-dienes. In: 252nd American Chemical Society National Meeting & Exposition, 21-25 August 2016, Philadelphia, PA. https://resolver.caltech.edu/CaltechAUTHORS:20160913-123515387
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Abstract
A method for olefin metathesis between 3(E)-1,3-dienes and terminal olefins is described. The method employs a recently reported ruthenium-based catalyst contg. a cyclometalated NHC ligand and takes advantage of its pronounced selectivity for terminal olefins in the presence of internal E-olefins. A wide variety of functional groups can be tolerated. Applications of the reaction include direct synthesis of insect pheromones from commerical precursor.
| Item Type: | Conference or Workshop Item (Paper) | ||||||||
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| Additional Information: | © 2016 American Chemical Society. | ||||||||
| Record Number: | CaltechAUTHORS:20160913-123515387 | ||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160913-123515387 | ||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||
| ID Code: | 70312 | ||||||||
| Collection: | CaltechAUTHORS | ||||||||
| Deposited By: | Tony Diaz | ||||||||
| Deposited On: | 30 Sep 2016 19:01 | ||||||||
| Last Modified: | 03 Oct 2019 10:29 |
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