Day, Michael W. and Wilhelm, Thomas E. and Grubbs, Robert H. (1996) A Diphenylcyclopropene Complex of Tungsten, [WCl_2O(PMePh_2)_2(η^2-3,3-diphenylcyclopropene)], Precursor to a Tungsten–Oxo–Olefin Metathesis Catalyst. Acta Crystallographica Section C, 52 (10). pp. 2460-2462. ISSN 0108-2701. doi:10.1107/S0108270196006464. https://resolver.caltech.edu/CaltechAUTHORS:20160913-131133401
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Abstract
The title compound, dichlorobis(methyldiphenylphosphine-P) [(1,2-[η])-3,3-diphenylcyclopropene]oxotungsten, [WCl_2O(C_(15)H_(12))(C_(13)H_(13)P)_2], is a mononuclear complex of tungsten with an approximately octahedral environment around the metal atom. The ligand, 3,3-diphenylcyclopropene, is bonded to the W atom in a [η]^2-geometry with effectively identical metal-to-carbon bond distances [W-C1 = 2.133 (7) Å and W-C2 2.131 (7) Å].
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| Additional Information: | © 1996 International Union of Crystallography. Received 6 March 1996; accepted 15 May 1996. The authors thank the NSF for Grant CHE-8219039 to purchase the diffractometer. | ||||||||||||
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| Issue or Number: | 10 | ||||||||||||
| DOI: | 10.1107/S0108270196006464 | ||||||||||||
| Record Number: | CaltechAUTHORS:20160913-131133401 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160913-131133401 | ||||||||||||
| Official Citation: | Day, M. W., Wilhelm, T. E. and Grubbs, R. H. (1996), A Diphenylcyclopropene Complex of Tungsten, [WCl2O(PMePh2)2(η2-3,3-diphenylcyclopropene)], Precursor to a Tungsten–Oxo–Olefin Metathesis Catalyst. Acta Crystallographica Section C, 52: 2460–2462. doi: 10.1107/S0108270196006464 | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 70318 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Ruth Sustaita | ||||||||||||
| Deposited On: | 13 Sep 2016 23:18 | ||||||||||||
| Last Modified: | 11 Nov 2021 04:27 |
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