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A platinum chloro (fluoroaryl)phosphine complex

Schaefer, William P. and Lyon, David K. and Labinger, Jay A. and Bercaw, John E. (1992) A platinum chloro (fluoroaryl)phosphine complex. Acta Crystallographica Section C, 48 (9). pp. 1582-1584. ISSN 0108-2701. doi:10.1107/S0108270192001008.

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trans-Dichloro bis[ tris(peritafluorophenyl)phosphine ]platinum(II), [PtCl_2{P(C_6F_5)_3}_2], M_r = 1330.29, triclinic, Pl, ɑ = 9.536 (4), b = 11.221 (2), c = 11.613 (1)Å, ɑ = 62.55 (1), β = 65.81 (2), y = 73.05 (2)º, V = 997.8 (4) Å^3, Z = 1, D_x = 2.21 g cm^(-3), λ(Mo Kɑ)= 0.71073 A, μ = 39.27 cm^(-1), F(000) = 628, room temperature, R = 0.034 for 3497 reflections with F_o^2 > 0. The molecule is centrosymmetric, with Pt-Cl distance 2.304 (2) and Pt-P 2.280 (1) Å, and P-Pt-Cl angle 94.8 (1)°. The C-P distances average 1.824 (4)Å, slightly longer than normal, and the pentafluoro-phenyl groups all have small [116.3 (3)º] angles at the c atom bonded to P.

Item Type:Article
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Labinger, Jay A.0000-0002-1942-9232
Additional Information:© 1992 International Union of Crystallography. Received 27 September 1991; accepted 21 January 1992. This work was supported by the Office of Naval Research (Grant No. N00014-89-J-3198), which is gratefully acknowledged.
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Office of Naval Research (ONR)N00014-89-J-3198
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Caltech Division of Chemistry and Chemical Engineering8515
Issue or Number:9
Record Number:CaltechAUTHORS:20160914-100611088
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Official Citation:Schaefer, W. P., Lyon, D. K., Labinger, J. A. and Bercaw, J. E. (1992), A platinum chloro (fluoroaryl)phosphine complex. Acta Crystallographica Section C, 48: 1582–1584. doi: 10.1107/S0108270192001008
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:70340
Deposited By: Ruth Sustaita
Deposited On:29 Sep 2016 23:25
Last Modified:11 Nov 2021 04:27

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