Schaefer, William P. and Lyon, David K. and Labinger, Jay A. and Bercaw, John E. (1992) A platinum chloro (fluoroaryl)phosphine complex. Acta Crystallographica Section C, 48 (9). pp. 1582-1584. ISSN 0108-2701. doi:10.1107/S0108270192001008. https://resolver.caltech.edu/CaltechAUTHORS:20160914-100611088
![]() |
PDF
- Published Version
See Usage Policy. 275kB |
![]() |
Crystallographic Info File (CIF) (Contains datablocks text, hh0588a)
- Supplemental Material
See Usage Policy. 5kB |
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20160914-100611088
Abstract
trans-Dichloro bis[ tris(peritafluorophenyl)phosphine ]platinum(II), [PtCl_2{P(C_6F_5)_3}_2], M_r = 1330.29, triclinic, Pl, ɑ = 9.536 (4), b = 11.221 (2), c = 11.613 (1)Å, ɑ = 62.55 (1), β = 65.81 (2), y = 73.05 (2)º, V = 997.8 (4) Å^3, Z = 1, D_x = 2.21 g cm^(-3), λ(Mo Kɑ)= 0.71073 A, μ = 39.27 cm^(-1), F(000) = 628, room temperature, R = 0.034 for 3497 reflections with F_o^2 > 0. The molecule is centrosymmetric, with Pt-Cl distance 2.304 (2) and Pt-P 2.280 (1) Å, and P-Pt-Cl angle 94.8 (1)°. The C-P distances average 1.824 (4)Å, slightly longer than normal, and the pentafluoro-phenyl groups all have small [116.3 (3)º] angles at the c atom bonded to P.
Item Type: | Article | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Related URLs: |
| ||||||||||||
ORCID: |
| ||||||||||||
Additional Information: | © 1992 International Union of Crystallography. Received 27 September 1991; accepted 21 January 1992. This work was supported by the Office of Naval Research (Grant No. N00014-89-J-3198), which is gratefully acknowledged. | ||||||||||||
Funders: |
| ||||||||||||
Other Numbering System: |
| ||||||||||||
Issue or Number: | 9 | ||||||||||||
DOI: | 10.1107/S0108270192001008 | ||||||||||||
Record Number: | CaltechAUTHORS:20160914-100611088 | ||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160914-100611088 | ||||||||||||
Official Citation: | Schaefer, W. P., Lyon, D. K., Labinger, J. A. and Bercaw, J. E. (1992), A platinum chloro (fluoroaryl)phosphine complex. Acta Crystallographica Section C, 48: 1582–1584. doi: 10.1107/S0108270192001008 | ||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
ID Code: | 70340 | ||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||
Deposited By: | Ruth Sustaita | ||||||||||||
Deposited On: | 29 Sep 2016 23:25 | ||||||||||||
Last Modified: | 11 Nov 2021 04:27 |
Repository Staff Only: item control page