A platinum chloro (fluoroaryl)phosphine complex

Schaefer, William P. and Lyon, David K. and Labinger, Jay A. and Bercaw, John E. (1992) A platinum chloro (fluoroaryl)phosphine complex. Acta Crystallographica Section C, 48 (9). pp. 1582-1584. ISSN 0108-2701. doi:10.1107/S0108270192001008. https://resolver.caltech.edu/CaltechAUTHORS:20160914-100611088

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Abstract

trans-Dichloro bis[ tris(peritafluorophenyl)phosphine ]platinum(II), [PtCl_2{P(C_6F_5)_3}_2], M_r = 1330.29, triclinic, Pl, ɑ = 9.536 (4), b = 11.221 (2), c = 11.613 (1)Å, ɑ = 62.55 (1), β = 65.81 (2), y = 73.05 (2)º, V = 997.8 (4) Å^3, Z = 1, D_x = 2.21 g cm^(-3), λ(Mo Kɑ)= 0.71073 A, μ = 39.27 cm^(-1), F(000) = 628, room temperature, R = 0.034 for 3497 reflections with F_o^2 > 0. The molecule is centrosymmetric, with Pt-Cl distance 2.304 (2) and Pt-P 2.280 (1) Å, and P-Pt-Cl angle 94.8 (1)°. The C-P distances average 1.824 (4)Å, slightly longer than normal, and the pentafluoro-phenyl groups all have small [116.3 (3)º] angles at the c atom bonded to P.

Item Type:

Article

Related URLs:

URL	URL Type	Description
http://dx.doi.org/10.1107/S0108270192001008	DOI	Article
http://scripts.iucr.org/cgi-bin/paper?S0108270192001008	Publisher	Article
http://onlinelibrary.wiley.com/doi/10.1107/S0108270192001008/abstract	Publisher	Article

ORCID:

Author	ORCID
Labinger, Jay A.	0000-0002-1942-9232

Additional Information:

© 1992 International Union of Crystallography. Received 27 September 1991; accepted 21 January 1992. This work was supported by the Office of Naval Research (Grant No. N00014-89-J-3198), which is gratefully acknowledged.

Funders:

Funding Agency	Grant Number
Office of Naval Research (ONR)	N00014-89-J-3198

Other Numbering System:

Other Numbering System Name	Other Numbering System ID
Caltech Division of Chemistry and Chemical Engineering	8515

Issue or Number:

DOI:

10.1107/S0108270192001008

Record Number:

CaltechAUTHORS:20160914-100611088

Persistent URL:

https://resolver.caltech.edu/CaltechAUTHORS:20160914-100611088

Official Citation:

Schaefer, W. P., Lyon, D. K., Labinger, J. A. and Bercaw, J. E. (1992), A platinum chloro (fluoroaryl)phosphine complex. Acta Crystallographica Section C, 48: 1582–1584. doi: 10.1107/S0108270192001008

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ID Code:

70340

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CaltechAUTHORS

Deposited By:

Ruth Sustaita

Deposited On:

29 Sep 2016 23:25

Last Modified:

11 Nov 2021 04:27

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