Schaefer, William P. and Connick, William B. and Miskowski, Vincent M. and Gray, Harry B. (1992) A Bis(pyrazolyl)(bipyridyl)platinum Complex. Acta Crystallographica Section C, 48 (10). pp. 1776-1778. ISSN 0108-2701. doi:10.1107/S0108270192002026. https://resolver.caltech.edu/CaltechAUTHORS:20160914-141706072
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Abstract
(4,4' -Dimethyl-2,2'-bipyridyl)bis(3,5-dimethylpyrazolium) platinum(II) 0.5-tetrahydrofuran solvate monohydrate, [Pt(C_5H_7N_2MC_(12)H_(12)-N2)].0.5C_4H_80.H_2O, M_r = 623.65, monoclinic, P2_1/n, ɑ = 8.625 (2), b = 20.593 (8), c = 14.451(4) Å, β = 90.32 (2)°, v = 2566.7 (14) Å^3, Z = 4, D_x = 1.61 g cm^(-3), λ(Mo Kɑ)= 0.71073 Å, μ = 55.50 cm^(-1), F(000) = 1232, room temperature, R = 0.0387 for 2874 reflections with F_o^2 > 3σ(F_o^2). The square-planar Pt complex has normal Pt-N(bipyridyl) bonds [2.009 (8) Å] and slightly short Pt-N(pyrazolyl) bonds [1.983 (7) Å]. The ligand molecules have normal distances and angles; the planes of the pyrazolyl ligands are twisted by about 60° to the bipyridyl-Pt plane, with the closest contacts between the pyrazolyls being -3.3 Å (Cl4···N5 and C19···N3).
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| Additional Information: | © 1992 International Union of Crystallography. Received 26 December 1991; accepted 11 February 1992. This research was supported by the Office of Naval Research. | ||||||||||||
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| Issue or Number: | 10 | ||||||||||||
| DOI: | 10.1107/S0108270192002026 | ||||||||||||
| Record Number: | CaltechAUTHORS:20160914-141706072 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160914-141706072 | ||||||||||||
| Official Citation: | Schaefer, W. P., Connick, W. B., Miskowski, V. M. and Gray, H. B. (1992), A bis(pyrazolyl)(bipyridyl)platinum complex. Acta Crystallographica Section C, 48: 1776–1778. doi: 10.1107/S0108270192002026 | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 70352 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Ruth Sustaita | ||||||||||||
| Deposited On: | 29 Sep 2016 23:35 | ||||||||||||
| Last Modified: | 11 Nov 2021 04:27 |
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