Schaefer, William P. and Krotz, Achim H. and Kuo, Louis Y. and Shields, Thomas P. and Barton, Jacqueline K. (1992) Metallointercalators: structure of rac-bis(ethylenediamine)(9,10-phenanthrenequinone diimine)rhodium(III) tribromide trihydrate. Acta Crystallographica Section C, 48 (11). pp. 2071-2073. ISSN 0108-2701. doi:10.1107/S0108270192006917. https://resolver.caltech.edu/CaltechAUTHORS:20160914-152612759
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Abstract
Bis(ethylenediamine)(phenanthrenequinone diimine)rhodium(III) tribromide trihydrate has a nearly planar phenanthrenequinone diimine ligand and two ordered ethylenediamine ligands, giving a distorted octahedral coordination to the compound. The N-Rh-N angles range from 77.1 (6) to 96.5°, with the largest deviations from 90° associated with the N atoms of the phenanthrenequinone diimine ligand. The two Rh-N distances involving these N atoms are 0.05 Å shorter than Rh-N distances to ethylenediamine ligands; other distances and angles are within normal ranges.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1992 International Union of Crystallography. Received 13 March 1992; accepted 26 June 1992. | |||||||||
| Issue or Number: | 11 | |||||||||
| DOI: | 10.1107/S0108270192006917 | |||||||||
| Record Number: | CaltechAUTHORS:20160914-152612759 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160914-152612759 | |||||||||
| Official Citation: | Schaefer, W. P., Krotz, A. H., Kuo, L. Y., Shields, T. P. & Barton, J. K. (1992). Acta Cryst. C48, 2071-2073 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 70356 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 29 Sep 2016 23:19 | |||||||||
| Last Modified: | 11 Nov 2021 04:28 |
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