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Copper(II) and Nickel(II) Octabromo-tetrakis(pentafluorophenyl)Porphyrin Complexes

Henling, Lawrence M. and Schaefer, William P. and Hodge, Julia A. and Hughes, Maureen E. and Gray, Harry B. and Lyons, James E. and Ellis, Paul E. Jr. (1993) Copper(II) and Nickel(II) Octabromo-tetrakis(pentafluorophenyl)Porphyrin Complexes. Acta Crystallographica Section C, 49 (10). pp. 1743-1747. ISSN 0108-2701. https://resolver.caltech.edu/CaltechAUTHORS:20160920-071508932

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Abstract

The copper and nickel complexes of 2,3,7,8,12,13,17, 18-octabromo-5,10,15,20-tetrakis(pentaftuorophenyl) porphyrin ({4,5,9,10,14,15,19,20-octabromo-2,7,12,17-tetrakis(pentaftuorophenyl)-21,22,23,24-tetraazapentacyclo[l6.2.1.1^(3,6).l^(8,11).l^(13,16)]tetracosa-l,3-(22),4,6,8(23),9,11,13(24),14,16,18(21),19-dodecaene }copper(II) 0.5-dichloromethane solvate and {4,5,9,10,14,15,19,20-octabromo-2,7,12,17-tetrakis(pentaftuorophenyl)-21,22,23,24-tetraazapentacyclo( 16.2.1.1^(3,6).l^(8,11).l^(13,16)]tetracosa-l,3(22),4,6,8(23),9,ll,13(24),14,16,18(21),19-dodecaene} nickel(II)0.5-dichloromethane solvate) form isostructural crystals. There is significant distortion from planarity of the porphyrin ring caused by the octabromo substituents interacting with the meso-pentafluorophenyl groups and with each other, with departures of the Br atoms from the plane defined by the four N atoms of up to 2.36 A. This tetrahedral distortion of the molecule does not result in any significant changes in bond distances from those in non-halogenated tetraphenylporphyrin complexes.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1107/S0108270193003051DOIArticle
http://scripts.iucr.org/cgi-bin/paper?S0108270193003051PublisherArticle
http://onlinelibrary.wiley.com/doi/10.1107/S0108270193003051/abstractPublisherArticle
ORCID:
AuthorORCID
Hodge, Julia A.0000-0001-6586-8845
Gray, Harry B.0000-0002-7937-7876
Additional Information:© 1993 International Union of Crystallography. Received 6 May 1992; accepted 23 March 1993. This work was supported by the US Department of Energy, Morgantown Energy Technology Center, the Gas Research Institute and Sun Company, Inc.
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)UNSPECIFIED
Gas Research InstituteUNSPECIFIED
Sun Company Inc.UNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Division of Chemistry and Chemical Engineering8624
Issue or Number:10
Record Number:CaltechAUTHORS:20160920-071508932
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160920-071508932
Official Citation:Henling, L. M., Schaefer, W. P., Hodge, J. A., Hughes, M. E., Gray, H. B., Lyons, J. E. and Ellis, P. E. (1993), Copper(II) and nickel(II) octabromo-tetrakis(pentafluorophenyl)porphyrin complexes. Acta Crystallographica Section C, 49: 1743–1747. doi: 10.1107/S0108270193003051
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:70446
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:29 Sep 2016 22:47
Last Modified:09 Mar 2020 13:18

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