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Real-time measurements of IVR versus inferences from spectral broadening data: the alkylanilines “ring + tail” system

Baskin, J. S. and Dantus, M. and Zewail, A. H. (1986) Real-time measurements of IVR versus inferences from spectral broadening data: the alkylanilines “ring + tail” system. Chemical Physics Letters, 130 (6). pp. 473-481. ISSN 0009-2614. https://resolver.caltech.edu/CaltechAUTHORS:20160920-093337135

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Abstract

We report on picosecond/molecular beam studies of alkylanilines. The studies reveal important discrepancies between real-time measurements and inferences from spectral broadening data. We observe quantum recurrences and we find that the observed severe spectral congestion does not correspond to the observed coherence. The effect of mode symmetry and energy on IVR dynamics is also examined.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0009-2614(86)80242-1DOIArticle
http://www.sciencedirect.com/science/article/pii/0009261486802421PublisherArticle
Additional Information:© 1986 Elsevier B.V. Received 19 August 1986, in final form 27 August 1986. This work is supported by the National Science Foundation under Grant CHE-8512887. We wish to thank the group of Professor W.A. Goddard III for helping us to produce fig. 1 and Professor R.B. Bernstein for very helpful suggestions.
Funders:
Funding AgencyGrant Number
NSFCHE-8512887
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Arthur Amos Noyes Laboratory of Chemical Physics7458
Issue or Number:6
Record Number:CaltechAUTHORS:20160920-093337135
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160920-093337135
Official Citation:J.S. Baskin, M. Dantus, A.H. Zewail, Real-time measurements of IVR versus inferences from spectral broadening data: the alkylanilines “ring + tail” system, Chemical Physics Letters, Volume 130, Issue 6, 24 October 1986, Pages 473-481, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(86)80242-1. (http://www.sciencedirect.com/science/article/pii/0009261486802421)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:70458
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:29 Sep 2016 21:17
Last Modified:03 Oct 2019 10:31

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