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Rephasing of Collisionless Molecular Rotational Coherence in Large Molecules

Felker, P. M. and Baskin, J. S. and Zewail, A. H. (1986) Rephasing of Collisionless Molecular Rotational Coherence in Large Molecules. Journal of Physical Chemistry, 90 (5). pp. 724-728. ISSN 0022-3654. doi:10.1021/j100277a006. https://resolver.caltech.edu/CaltechAUTHORS:20160920-105242840

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Abstract

We present experimental results on the rephasing of collisionless rotational coherence in jet-cooled trans-stitbene. The results represent the first observation of quantum coherence effects arising from the rotational level structure of molecules. We discuss the nature of the effect, its possible influence in time-resolved polarization experiments designed to probe intramolecular energy flow, and its possible uses as a new spectroscopic tool.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/j100277a006DOIArticle
http://pubs.acs.org/doi/abs/10.1021/j100277a006PublisherArticle
Additional Information:© 1986 American Chemical Society. Received: January 3, 1986. We thank the National Science Foundation for support of this work through Grant No. DMR-8521191.
Funders:
Funding AgencyGrant Number
NSFDMR-8521191
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Arthur Amos Noyes Laboratory of Chemical Physics7354
Issue or Number:5
DOI:10.1021/j100277a006
Record Number:CaltechAUTHORS:20160920-105242840
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160920-105242840
Official Citation:Rephasing of collisionless molecular rotational coherence in large molecules P. M. Felker, J. S. Baskin, and A. H. Zewail The Journal of Physical Chemistry 1986 90 (5), 724-728 DOI: 10.1021/j100277a006
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:70464
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:30 Sep 2016 18:47
Last Modified:11 Nov 2021 04:29

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