Felker, Peter M. and Zewail, Ahmed H. (1984) Direct picosecond time resolution of dissipative intramolecular vibrational-energy redistribution (IVR) in isolated molecules. Chemical Physics Letters, 108 (4). pp. 303-310. ISSN 0009-2614. doi:10.1016/0009-2614(84)85196-9. https://resolver.caltech.edu/CaltechAUTHORS:20160921-075400461
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Abstract
Direct picosecond time resolution of dissipative IVR is reported for the first time. For jet-cooled anthracene with E_(vib) = 1792 cm^(−1), the unrelaxed fluorescence displays a fast decay of ≈75 ps, while the relaxed fluorescence displays a corresponding rise. The onset for dissipative IVR is related to the effective density of states and coupling matrix elements, and reflects the importance of time-resolved measurements.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1984 Elsevier Science Publishers B.V. Received 22 May 1984. This material is based upon work supported by the National Science Foundation under Grant No. CHE-8211356. | |||||||||
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| Issue or Number: | 4 | |||||||||
| DOI: | 10.1016/0009-2614(84)85196-9 | |||||||||
| Record Number: | CaltechAUTHORS:20160921-075400461 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160921-075400461 | |||||||||
| Official Citation: | Peter M. Felker, Ahmed H. Zewail, Direct picosecond time resolution of dissipative intramolecular vibrational-energy redistribution (IVR) in isolated molecules, Chemical Physics Letters, Volume 108, Issue 4, 13 July 1984, Pages 303-310, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(84)85196-9. (http://www.sciencedirect.com/science/article/pii/0009261484851969) | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 70483 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 29 Sep 2016 20:35 | |||||||||
| Last Modified: | 11 Nov 2021 04:30 |
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