Bersohn, R. and Zewail, A. H. (1988) Time Dependent Absorption of Fragments During Dissociation. Berichte der Bunsengesellschaft für physikalische Chemie, 92 (3). pp. 373-378. ISSN 0005-9021. doi:10.1002/bbpc.198800076. https://resolver.caltech.edu/CaltechAUTHORS:20160926-075414529
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20160926-075414529
Abstract
The development of methods of generation of very short pulses of light with widths about or below 100 fs has enabled the measurement of the rate of direct photodissociation of a bond. The experiment measures absorption as a function of both time and the degree to which the probing light is off resonance with one of the fragments. A classical model with an exponential repulsion is used to relate experimental observables to the dissociation time and properties of the potential surface. The delicateness of the probe will improve as the photon energy approaches the threshold energy for dissociation.
Item Type: | Article | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
Related URLs: |
| |||||||||
Additional Information: | © 1988 Wiley-VCH Verlag GmbH & Co. Funded by Air Force Office of Scientific Research. Grant Number: AFOSR-87-0071 (A.H.Z.). National Science Foundation (R. B.) Contribution No. 7689. | |||||||||
Funders: |
| |||||||||
Subject Keywords: | Chemical Bond;Light. Absorption | |||||||||
Other Numbering System: |
| |||||||||
Issue or Number: | 3 | |||||||||
DOI: | 10.1002/bbpc.198800076 | |||||||||
Record Number: | CaltechAUTHORS:20160926-075414529 | |||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160926-075414529 | |||||||||
Official Citation: | Bersohn, R. and Zewail, A. H. (1988), Time Dependent Absorption of Fragments During Dissociation. Berichte der Bunsengesellschaft für physikalische Chemie, 92: 373–378. doi: 10.1002/bbpc.198800076 | |||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
ID Code: | 70578 | |||||||||
Collection: | CaltechAUTHORS | |||||||||
Deposited By: | Ruth Sustaita | |||||||||
Deposited On: | 28 Sep 2016 23:28 | |||||||||
Last Modified: | 11 Nov 2021 04:31 |
Repository Staff Only: item control page