Hochstrasser, Robin M. and Lin, T. S. and Zewail, Ahmed H. (1972) Mixed Magnetic and Electric Dipole Transition in s-Triazine. Journal of Chemical Physics, 56 (1). pp. 637-639. ISSN 0021-9606. doi:10.1063/1.1676916. https://resolver.caltech.edu/CaltechAUTHORS:20160928-081727482
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Abstract
We have shown that the radiation pattern for absorption to the lowest energy excited singlet state of s‐triazine corresponds to that of a mixed electric and magnetic dipole transition. This was done by demonstrating, for the first time with an organic, the classic procedure of obtaining absorption coefficients for different k, ε̂, and Ĥ for a uniaxial arrangement of molecules. We find the 30 014 cm^(−1) transition of s‐triazine to be 26% magnetic and 74% electric dipole, hence the state symmetry is ^1 E in the crystal field, and ^1 E″ in the free molecule (D_(3h) ).
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| Additional Information: | © 1972 The American Institute of Physics. Received 12 August 1971. This research was supported by a Department of Health Grant GM 12592 and by the Laboratory for Research on the Structure of Matter through an A.R.P.A. grant to the University of Pennsylvania. | |||||||||
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| Issue or Number: | 1 | |||||||||
| DOI: | 10.1063/1.1676916 | |||||||||
| Record Number: | CaltechAUTHORS:20160928-081727482 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160928-081727482 | |||||||||
| Official Citation: | Mixed Magnetic and Electric Dipole Transition in s‐Triazine Hochstrasser, Robin M. and Lin, T. S. and Zewail, Ahmed H., The Journal of Chemical Physics, 56, 637-639 (1972), DOI:http://dx.doi.org/10.1063/1.1676916 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 70632 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 28 Sep 2016 22:33 | |||||||||
| Last Modified: | 11 Nov 2021 04:32 |
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