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Mixed Magnetic and Electric Dipole Transition in s-Triazine

Hochstrasser, Robin M. and Lin, T. S. and Zewail, Ahmed H. (1972) Mixed Magnetic and Electric Dipole Transition in s-Triazine. Journal of Chemical Physics, 56 (1). pp. 637-639. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:20160928-081727482

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Abstract

We have shown that the radiation pattern for absorption to the lowest energy excited singlet state of s‐triazine corresponds to that of a mixed electric and magnetic dipole transition. This was done by demonstrating, for the first time with an organic, the classic procedure of obtaining absorption coefficients for different k, ε̂, and Ĥ for a uniaxial arrangement of molecules. We find the 30 014 cm^(−1) transition of s‐triazine to be 26% magnetic and 74% electric dipole, hence the state symmetry is ^1 E in the crystal field, and ^1 E″ in the free molecule (D_(3h) ).


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1063/1.1676916DOIArticle
http://scitation.aip.org/content/aip/journal/jcp/56/1/10.1063/1.1676916PublisherArticle
Additional Information:© 1972 The American Institute of Physics. Received 12 August 1971. This research was supported by a Department of Health Grant GM 12592 and by the Laboratory for Research on the Structure of Matter through an A.R.P.A. grant to the University of Pennsylvania.
Funders:
Funding AgencyGrant Number
NIHGM 12592
Advanced Research Projects Agency (ARPA)UNSPECIFIED
Record Number:CaltechAUTHORS:20160928-081727482
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20160928-081727482
Official Citation:Mixed Magnetic and Electric Dipole Transition in s‐Triazine Hochstrasser, Robin M. and Lin, T. S. and Zewail, Ahmed H., The Journal of Chemical Physics, 56, 637-639 (1972), DOI:http://dx.doi.org/10.1063/1.1676916
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:70632
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:28 Sep 2016 22:33
Last Modified:28 Sep 2016 22:33

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