Hochstrasser, R. M. and Zewail, A. H. (1971) Stark and zeeman effects on the singlet nπ^* state of s-triazine. Chemical Physics Letters, 11 (2). pp. 157-158. ISSN 0009-2614. doi:10.1016/0009-2614(71)80345-7. https://resolver.caltech.edu/CaltechAUTHORS:20160928-081727718
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Abstract
The lowest singlet state of s-triazine is characterized as ^1E″ arising from e′ → e″ promotion (n → π^*). The state has angular momentum corresponding to g = 0.24. The state is also subject to a first-order Stark effect (α = 0.53D) due to electric field induced interactions of 2s and 2p electrons. We report on the electric and magnetic field splittings, and a brief theoretical description of these effects.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1971 Elsevier B.V. Received 28 July 1971. This research was supported in part by National Institutes of Health grant: GM12592, and in part by the Laboratory for Research on the Structure of Matter through an ARPA grant to the University of Pennsylvania. | |||||||||
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| Issue or Number: | 2 | |||||||||
| DOI: | 10.1016/0009-2614(71)80345-7 | |||||||||
| Record Number: | CaltechAUTHORS:20160928-081727718 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160928-081727718 | |||||||||
| Official Citation: | R.M. Hochstrasser, A.H. Zewail, Stark and zeeman effects on the singlet nπ* state of s-triazine, Chemical Physics Letters, Volume 11, Issue 2, 1 October 1971, Pages 157-158, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(71)80345-7. (http://www.sciencedirect.com/science/article/pii/0009261471803457) | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 70633 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 28 Sep 2016 22:30 | |||||||||
| Last Modified: | 11 Nov 2021 04:32 |
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