Cao, J. and Ihee, H. and Zewail, A. H. (1998) Ultrafast electron diffraction: determination of radical structure with picosecond time resolution. Chemical Physics Letters, 290 (1-3). pp. 1-8. ISSN 0009-2614. doi:10.1016/S0009-2614(98)00520-X. https://resolver.caltech.edu/CaltechAUTHORS:20160930-071851904
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Abstract
Using ultrafast electron diffraction (UED) with the temporal diffraction-difference method recently developed in this laboratory, we report accurate determination of the radical (CF_2) structure in the dissociation of diiododifluoromethane (CF_2I_2) with picosecond time resolution. Time-zero was clocked accurately within 2 ps and both iodine atoms were found to be liberated in less than 4 ps. The structure, absolute fraction, and electronic state of the radical were determined. The CF_2 radical was found to be in X^1A_1 ground state with C–F and F⋯F distances of 1.30(±0.02) Å and 2.06(±0.06) Å, respectively.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1998 Elsevier B.V. Received 15 April 1998, Revised 24 April 1998, Available online 28 July 1998. This research was supported by a grant from Air force Office of Scientific Research and the Office of Naval Research. | |||||||||
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| Issue or Number: | 1-3 | |||||||||
| DOI: | 10.1016/S0009-2614(98)00520-X | |||||||||
| Record Number: | CaltechAUTHORS:20160930-071851904 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160930-071851904 | |||||||||
| Official Citation: | J. Cao, H. Ihee, A.H. Zewail, Ultrafast electron diffraction: determination of radical structure with picosecond time resolution, Chemical Physics Letters, Volume 290, Issues 1–3, 26 June 1998, Pages 1-8, ISSN 0009-2614, http://dx.doi.org/10.1016/S0009-2614(98)00520-X. (http://www.sciencedirect.com/science/article/pii/S000926149800520X) | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 70671 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 30 Sep 2016 17:12 | |||||||||
| Last Modified: | 11 Nov 2021 04:33 |
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