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Enhanced Absorption and <1% Spectrum-and-Angle-Averaged Reflection in Tapered Microwire Arrays

Yalamanchili, Sisir and Emmer, Hal S. and Fountaine, Katherine T. and Chen, Christopher T. and Lewis, Nathan S. and Atwater, Harry A. (2016) Enhanced Absorption and <1% Spectrum-and-Angle-Averaged Reflection in Tapered Microwire Arrays. ACS Photonics, 3 (10). pp. 1854-1861. ISSN 2330-4022. http://resolver.caltech.edu/CaltechAUTHORS:20161003-084500313

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Abstract

We report ordered, high aspect ratio, tapered Si microwire arrays that exhibit an extremely low angular (0° to 50°) and spectrally averaged reflectivity of <1% of the incident 400–1100 nm illumination. After isolating the microwires from the substrate with a polymer infill and peel off process, the arrays were found to absorb 89.1% of angular averaged incident illumination (0° to 50°) in the equivalent volume of a 20 μm thick Si planar slab, reaching 99.5% of the classical light trapping limit between 400 and 1100 nm. We explain the broadband absorption by enhancement in coupling to waveguide modes due to the tapered microstructure of the arrays. Time-resolved microwave photoconductivity decay measurements yielded charge-carrier lifetimes of 0.75 μs (more than an order of magnitude higher than vapor–liquid–solid-grown Si microwires) in the tapered microwires, resulting in an implied V_(oc) of 0.655 V. The high absorption and high aspect ratio in these ordered microwire arrays make them an attractive platform for high-efficiency thin-film crystalline Si solar cells and as well as for the photoelectrochemical production of fuels from sunlight.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/acsphotonics.6b00370DOIArticle
http://pubs.acs.org/doi/abs/10.1021/acsphotonics.6b00370PublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/acsphotonics.6b00370PublisherSupporting Information
ORCID:
AuthorORCID
Fountaine, Katherine T.0000-0002-0414-8227
Chen, Christopher T.0000-0001-5848-961X
Lewis, Nathan S.0000-0001-5245-0538
Atwater, Harry A.0000-0001-9435-0201
Additional Information:© 2016 American Chemical Society. Received: May 30, 2016; Publication Date (Web): September 19, 2016. This work was supported in part by the National Science Foundation (NSF) and the Department of Energy (DOE) under NSF CA No. EEC-1041895 (H.S.E. and C.T.C.) and Joint Center for Artificial Photosynthesis, a DOE Energy Innovation Hub, supported through the Office of Science of the U.S. Department of Energy under Award No. DE-SC0004993. Some of us (C.T.C., H.A.A.) are also supported in part by the U.S. Department of Energy through the Bay Area Photovoltaic Consortium under Award Number DE-EE0004946. We thank Dennis Friedrich for his collaborations for microwave-detected photoconductive decay measurements, Prof. Shu Hu for stimulating discussions, and Carol Garland for her assistance with TEM. This work benefited from use of the Applied Physics and Materials Science Department’s Transmission Electron Microscopy Facility. Fabrication was performed in Kavli Nanoscience Institute (KNI) at Caltech, and we thank KNI staff for their assistance during fabrication. Lumerical FDTD simulations for this research used resources of the National Energy Research Scientific Computing Center, a DOE Office of Science User Facility supported by the Office of Science of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. S. Yalamanchili and H. S. Emmer contributed equally. The authors declare no competing financial interest.
Group:JCAP, Kavli Nanoscience Institute
Funders:
Funding AgencyGrant Number
NSFEEC-1041895
Department of Energy (DOE)DE-SC0004993
Department of Energy (DOE)DE-EE0004946
Department of Energy (DOE)DE-AC02-05CH11231
Subject Keywords:absorption; carrier lifetime; ICPRIE; microwires; reflection; silicon; surface passivation; waveguide
Record Number:CaltechAUTHORS:20161003-084500313
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20161003-084500313
Official Citation:Enhanced Absorption and <1% Spectrum-and-Angle-Averaged Reflection in Tapered Microwire Arrays Sisir Yalamanchili, Hal S. Emmer, Katherine T. Fountaine, Christopher T. Chen, Nathan S. Lewis, and Harry A. Atwater ACS Photonics 2016 3 (10), 1854-1861 DOI: 10.1021/acsphotonics.6b00370
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:70747
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:03 Oct 2016 16:57
Last Modified:22 Sep 2017 21:30

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