Guthrie, George, Jr. and Wilson, J. Norton and Schomaker, Verner (1949) Theory of the Thermal Diffusion of Electrolytes in a Clusius Column. Journal of Chemical Physics, 17 (3). pp. 310-313. ISSN 0021-9606. doi:10.1063/1.1747244. https://resolver.caltech.edu/CaltechAUTHORS:20161017-111308513
![[img]](https://authors.library.caltech.edu/style/images/fileicons/application_pdf.png) |
PDF
- Published Version
See Usage Policy. 606kB |
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20161017-111308513
Abstract
A theory is presented which accounts approximately for the apparently anomalous difference between the thermal diffusion coefficients of an ion in the presence and in the absence of other electrolytes; the theory is based on the existence of an electric field parallel to the thermal gradient in the electrolyte as a consequence of the variation in mobility among the various ions present. It is pointed out also that some data on the behavior of electrolytes in a Clusius column are at variance with the Debye exponential law concerning the steady‐state distribution of solute.
| Item Type: | Article | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| |||||||||
| Additional Information: | © 1949 American Institute of Physics. (Received August 30, 1948) The authors wish to express their appreciation to Professor J. G. Kirkwood and to Professor Leverett Davis, Jr., for helpful discussions and advice. | |||||||||
| Other Numbering System: |
| |||||||||
| Issue or Number: | 3 | |||||||||
| DOI: | 10.1063/1.1747244 | |||||||||
| Record Number: | CaltechAUTHORS:20161017-111308513 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20161017-111308513 | |||||||||
| Official Citation: | Theory of the Thermal Diffusion of Electrolytes in a Clusius Column Guthrie, George and Wilson, J. Norton and Schomaker, Verner, The Journal of Chemical Physics, 17, 310-313 (1949), DOI:http://dx.doi.org/10.1063/1.1747244 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 71165 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 17 Oct 2016 21:01 | |||||||||
| Last Modified: | 11 Nov 2021 04:40 |
Repository Staff Only: item control page
