Dekker, Albert O. and Dickinson, Roscoe G. (1940) Oxidation of Ascorbic Acid by Oxygen with Cupric Ion as Catalyst. Journal of the American Chemical Society, 62 (8). pp. 2165-2171. ISSN 0002-7863. doi:10.1021/ja01865a070. https://resolver.caltech.edu/CaltechAUTHORS:20161024-153716489
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Abstract
The experiments described in the present paper were carried out for the purpose of obtaining more specific information concerning the nature of the copper-catalyzed oxidation of ascorbic acid. All of the experiments reported here were carried out under such conditions that steps involving oxygen as a reactant were not rate determining. Furthermore, in order to avoid the possibility of cupric ion complexing with buffers no buffers were used, but instead the hydrogen-ion concentration was maintained at an effectively constant value throughout the course of the reaction by the addition of a comparatively large amount of acid at the start.
Item Type: | Article | |||||||||
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Additional Information: | © 1940 American Chemical Society. Received April 22, 1940. | |||||||||
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Issue or Number: | 8 | |||||||||
DOI: | 10.1021/ja01865a070 | |||||||||
Record Number: | CaltechAUTHORS:20161024-153716489 | |||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20161024-153716489 | |||||||||
Official Citation: | Oxidation of Ascorbic Acid by Oxygen with Cupric Ion as Catalyst Albert O. Dekker and Roscoe G. Dickinson Journal of the American Chemical Society 1940 62 (8), 2165-2171 DOI: 10.1021/ja01865a070 | |||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
ID Code: | 71410 | |||||||||
Collection: | CaltechAUTHORS | |||||||||
Deposited By: | George Porter | |||||||||
Deposited On: | 24 Oct 2016 22:52 | |||||||||
Last Modified: | 11 Nov 2021 04:44 |
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