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The one-electron oxidation product of a metallocenyl-terminated cyanine

Barlow, Stephen and Day, Michael W. and Marder, Seth R. (2000) The one-electron oxidation product of a metallocenyl-terminated cyanine. Acta Crystallographica Section C, 56 (3). pp. 303-304. ISSN 0108-2701. http://resolver.caltech.edu/CaltechAUTHORS:20161024-160855843

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Abstract

The 1-(2,3,4,5,1',2',3',4'-octa­methyl­ferrocen-1-yl)-3-(ruth­eno­cen­yl)­allylium cation readily undergoes one-electron oxidation to a dication in which an octa­methyl­ferrocenium moiety is bridged by a vinyl­ene group to a [(η^6-fulvene)(η^5-cyclo­penta­dienyl)­ruthenium]+ moiety. In the title compound, 1-(2,3,4,5,1',2',3',4'-octa­methyl­ferrocen-1-yl)-3-(ruth­eno­cen­ylidene)prop-1-enium(2+) bis­(tetra­fluoro­borate), [Fe­Ru­(C_5H_5)(C_9H_(13))(C_(17)H_(19))]­(BF_4)_2, the C-C bond lengths in the bridge (average for two independent mol­ecules) are, starting from the ipso octa­methyl­ferrocenium carbon and ending at the exo carbon of the coordinated fulvene, 1.455 (6), 1.344 (3) and 1.449 (8) Å, indicating a localized electronic structure.


Item Type:Article
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https://doi.org/10.1107/S0108270199015462DOIArticle
http://scripts.iucr.org/cgi-bin/paper?S0108270199015462PublisherArticle
Additional Information:© 2000 International Union of Crystallography. Received 21 September 1999. Accepted 29 November 1999. Support from the National Science Foundation, Air Force Office of Scientific Research (AFOSR), at Caltech is gratefully acknowledged. The research described in this paper was performed in part by the Jet Propulsion Laboratory (JPL), California Institute of Technology, as part of its Center for Space Microelectronics Technology and was supported by the Ballistic Missile Defense Initiative Organization, Innovative Science and Technology Office, through an agreement with the National Aeronautics and Space Administration (NASA).
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NSFUNSPECIFIED
Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
NASA/JPL/CaltechUNSPECIFIED
Ballistic Missile Defense OrganizationUNSPECIFIED
Record Number:CaltechAUTHORS:20161024-160855843
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20161024-160855843
Official Citation:Barlow, S., Day, M. W. & Marder, S. R. (2000). Acta Cryst. C56, 303-304.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:71419
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:25 Oct 2016 15:04
Last Modified:25 Oct 2016 15:04

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