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Enhanced strength and temperature dependence of mechanical properties of Li at small length scales and its implications for Li metal anodes

Xu, Chen and Ahmad, Zeeshan and Aryanfar, Asghar and Viswanathan, Venkatasubramanian and Greer, Julia R. (2017) Enhanced strength and temperature dependence of mechanical properties of Li at small length scales and its implications for Li metal anodes. Proceedings of the National Academy of Sciences of the United States of America, 114 (1). pp. 57-61. ISSN 0027-8424. PMCID PMC5224391. http://resolver.caltech.edu/CaltechAUTHORS:20161025-111520333

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Abstract

Most next-generation Li ion battery chemistries require a functioning lithium metal (Li) anode. However, its application in secondary batteries has been inhibited because of uncontrollable dendrite growth during cycling. Mechanical suppression of dendrite growth through solid polymer electrolytes (SPEs) or through robust separators has shown the most potential for alleviating this problem. Studies of the mechanical behavior of Li at any length scale and temperature are limited because of its extreme reactivity, which renders sample preparation, transfer, microstructure characterization, and mechanical testing extremely challenging. We conduct nanomechanical experiments in an in situ scanning electron microscope and show that micrometer-sized Li attains extremely high strengths of 105 MPa at room temperature and of 35 MPa at 90 °C. We demonstrate that single-crystalline Li exhibits a power-law size effect at the micrometer and submicrometer length scales, with the strengthening exponent of −0.68 at room temperature and of −1.00 at 90 °C. We also report the elastic and shear moduli as a function of crystallographic orientation gleaned from experiments and first-principles calculations, which show a high level of anisotropy up to the melting point, where the elastic and shear moduli vary by a factor of ∼4 between the stiffest and most compliant orientations. The emergence of such high strengths in small-scale Li and sensitivity of this metal’s stiffness to crystallographic orientation help explain why the existing methods of dendrite suppression have been mainly unsuccessful and have significant implications for practical design of future-generation batteries.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1073/pnas.1615733114DOIArticle
http://www.pnas.org/content/114/1/57PublisherArticle
http://www.pnas.org/lookup/suppl/doi:10.1073/pnas.1615733114/-/DCSupplementalPublisherSupporting Information
https://arxiv.org/abs/1606.05826arXivDiscussion Paper
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5224391/PubMed CentralArticle
ORCID:
AuthorORCID
Xu, Chen0000-0002-9427-0161
Aryanfar, Asghar0000-0002-8890-077X
Greer, Julia R.0000-0002-9675-1508
Additional Information:© 2017 National Academy of Sciences. Edited by Alexis T. Bell, University of California, Berkeley, CA, and approved November 28, 2016 (received for review September 22, 2016). Published online before print December 19, 2016, doi: 10.1073/pnas.1615733114 We thank Dr. Chi Ma for EBSD assistance and useful discussions. We gratefully acknowledge the financial support of the US Department of Energy through J.R.G.'s Early Career Grant DE-SC0006599. This work was supported by National Science Foundation CAREER Award CBET-1554273 (to V.V.). Author contributions: C.X., Z.A., V.V., and J.R.G. designed research; C.X. and Z.A. performed research; A.A. contributed new reagents/analytic tools; C.X., Z.A., V.V., and J.R.G. analyzed data; and C.X., Z.A., V.V., and J.R.G. wrote the paper. The authors declare no conflict of interest. This article is a PNAS Direct Submission. This article contains supporting information online at www.pnas.org/lookup/suppl/doi:10.1073/pnas.1615733114/-/DCSupplemental.
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)DE-SC000659
NSFCBET-1554273
Subject Keywords:dendrite | size effect | elastic anisotropy | dislocation | elevated temperature
PubMed Central ID:PMC5224391
Record Number:CaltechAUTHORS:20161025-111520333
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20161025-111520333
Official Citation:Chen Xu, Zeeshan Ahmad, Asghar Aryanfar, Venkatasubramanian Viswanathan, and Julia R. Greer Enhanced strength and temperature dependence of mechanical properties of Li at small scales and its implications for Li metal anodes PNAS 2017 114 (1) 57-61; published ahead of print December 19, 2016, doi:10.1073/pnas.1615733114
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:71448
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:25 Oct 2016 19:06
Last Modified:31 Oct 2017 22:20

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