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Contrasting cloud composition between coupled and decoupled marine boundary layer clouds

Wang, Zhen and Ramirez, Marco Mora and Dadashazar, Hossein and MacDonald, Alex B. and Crosbie, Ewan and Bates, Kelvin H. and Coggon, Matthew M. and Craven, Jill S. and Lynch, Peng and Campbell, James R. and Azadi Aghdam, Mojtaba and Woods, Roy K. and Jonsson, Haflidi and Flagan, Richard C. and Seinfeld, John H. and Sorooshian, Armin (2016) Contrasting cloud composition between coupled and decoupled marine boundary layer clouds. Journal of Geophysical Research. Atmospheres, 121 (19). pp. 11679-11691. ISSN 2169-897X. http://resolver.caltech.edu/CaltechAUTHORS:20161202-131843652

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Abstract

Marine stratocumulus clouds often become decoupled from the vertical layer immediately above the ocean surface. This study contrasts cloud chemical composition between coupled and decoupled marine stratocumulus clouds for dissolved nonwater substances. Cloud water and droplet residual particle composition were measured in clouds off the California coast during three airborne experiments in July–August of separate years (Eastern Pacific Emitted Aerosol Cloud Experiment 2011, Nucleation in California Experiment 2013, and Biological and Oceanic Atmospheric Study 2015). Decoupled clouds exhibited significantly lower air-equivalent mass concentrations in both cloud water and droplet residual particles, consistent with reduced cloud droplet number concentration and subcloud aerosol (D_p > 100 nm) number concentration, owing to detachment from surface sources. Nonrefractory submicrometer aerosol measurements show that coupled clouds exhibit higher sulfate mass fractions in droplet residual particles, owing to more abundant precursor emissions from the ocean and ships. Consequently, decoupled clouds exhibited higher mass fractions of organics, nitrate, and ammonium in droplet residual particles, owing to effects of long-range transport from more distant sources. Sodium and chloride dominated in terms of air-equivalent concentration in cloud water for coupled clouds, and their mass fractions and concentrations exceeded those in decoupled clouds. Conversely, with the exception of sea-salt constituents (e.g., Cl, Na, Mg, and K), cloud water mass fractions of all species examined were higher in decoupled clouds relative to coupled clouds. Satellite and Navy Aerosol Analysis and Prediction System-based reanalysis data are compared with each other, and the airborne data to conclude that limitations in resolving boundary layer processes in a global model prevent it from accurately quantifying observed differences between coupled and decoupled cloud composition.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/2016JD025695DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/2016JD025695/abstractPublisherArticle
ORCID:
AuthorORCID
Bates, Kelvin H.0000-0001-7544-9580
Coggon, Matthew M.0000-0002-5763-1925
Lynch, Peng0000-0002-9661-8045
Azadi Aghdam, Mojtaba0000-0002-1720-2894
Jonsson, Haflidi0000-0003-3043-1074
Flagan, Richard C.0000-0001-5690-770X
Seinfeld, John H.0000-0003-1344-4068
Sorooshian, Armin0000-0002-2243-2264
Additional Information:© 2016 American Geophysical Union. Received 24 JUL 2016; Accepted 13 SEP 2016; Accepted article online 15 SEP 2016; Published online 1 OCT 2016. This work was funded by ONR grants N00014-11-1-0783, N00014-10-1-0200, N00014-04-1-0118, N00014-10-1-0811, and N00014-16-1-2567 and NSF grant AGS-1008848. Field campaign data used for this study can be obtained at u.arizona.edu/~armin, and questions about those data should be directed to the corresponding author (armin@email.arizona.edu). The NAAPS reanalysis data are available at http://usgodae.org/cgi-bin/datalist.pl?dset=nrl_naaps_reanalysis&summary=Go; the data on that server are updated as model improvements are made and reruns are completed. CALIOP data are available at the following website: https://eosweb.larc.nasa.gov/.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)N00014-11-1-0783
Office of Naval Research (ONR)N00014-10-1-0200
Office of Naval Research (ONR)N00014-04-1-0118
Office of Naval Research (ONR)N00014-10-1-0811
Office of Naval Research (ONR)N00014-16-1-2567
NSFAGS-1008848
Subject Keywords:cloud; composition; cloud water; marine; boundary layer; sea salt
Record Number:CaltechAUTHORS:20161202-131843652
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20161202-131843652
Official Citation:Wang, Z., et al. (2016), Contrasting cloud composition between coupled and decoupled marine boundary layer clouds, J. Geophys. Res. Atmos., 121, 11,679–11,691, doi:10.1002/2016JD025695
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:72529
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:02 Dec 2016 22:32
Last Modified:02 May 2017 21:37

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