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Photon and carrier management design for nonplanar thin-film copper indium gallium selenide photovoltaics

Bukowsky, Colton R. and Grandidier, Jonathan and Fountaine, Katherine T. and Callahan, Dennis M. and Stanbery, Billy J. and Atwater, Harry A. (2017) Photon and carrier management design for nonplanar thin-film copper indium gallium selenide photovoltaics. Solar Energy Materials and Solar Cells, 161 . pp. 149-156. ISSN 0927-0248.

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Nonplanar structured photovoltaic absorber design has potential to achieve high solar cell efficiency with significantly reduced material use. We report optoelectronic simulations that highlight photon and generated carrier management opportunities for improvement of thin film Cu(In_xGa_(1−x))Se_2 (CIGS) device performance. Structures realized via either self-assembly or patterning via nanoimprint lithography, and also a combination of both are predicted to exhibit significant increases in short circuit current density and open circuit voltage simultaneously. The structures investigated include: 1) self-assembled nonplanar structures that strongly scatter incident light and enhance carrier generation near regions of high electric potential, 2) lithographically-patterned embedded periodic dielectric structures, 3) planar dielectric layers that separate the CIGS absorber from the molybdenum back-contact via reduced-area contacts that minimize optical and electronic losses, 4) a combination of these for combined effects. We find that the self-assembled nonplanar CIGS cells with 700 nm planar equivalent thickness, combined with dielectric separation layers yield increases in short circuit current density and open circuit voltage up to 3.4 mA cm−2 and 29 mV, respectively. The absolute efficiency increases from 15.4% to 18.1%, compared to the predicted efficiency for planar CIGS thin film cells of equivalent thickness. The addition of a single layer MgF_2 anti-reflection coating brings the maximum predicted efficiency up to 19.7% for randomly textured devices.

Item Type:Article
Related URLs:
URLURL TypeDescription
Bukowsky, Colton R.0000-0003-3577-8050
Grandidier, Jonathan0000-0002-3384-6083
Fountaine, Katherine T.0000-0002-0414-8227
Atwater, Harry A.0000-0001-9435-0201
Additional Information:© 2016 Elsevier B.V. Received 15 June 2016, Revised 4 November 2016, Accepted 6 November 2016, Available online 3 December 2016. The authors thank Hal Emmer, Chris T. Chen, Yulia Tolstova, and Stefan Olmelcheko for helpful discussions. Dr. Stanbery acknowledges the HelioVolt team of co-inventors that developed the processing technology to create these nanotextured absorbers [10]. This work was supported by the U.S. Department of Energy and the Bay Area Photovoltaic Consortium under award number DE-EE0004946 (C.R.B. and D.M.C.) and the Joint Center for Artificial Photosynthesis (KT.F. and H.A.A.), a DOE Energy Innovation Hub, supported through the Office of Science of the U.S. Department of Energy under Award No. DE-SC0004993. K.T. Fountaine was supported by the National Science Foundation Graduate Research Fellowship under Grant No DE-SC0004993.
Funding AgencyGrant Number
Department of Energy (DOE)DE-EE0004946
Department of Energy (DOE)DE-SC0004993
NSF Graduate Research FellowshipDGE-1144469
Subject Keywords:Solar cells; Thin film; Light trapping; CIGS; Nanotextured
Record Number:CaltechAUTHORS:20161212-115220770
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Official Citation:Colton R. Bukowsky, Jonathan Grandidier, Katherine T. Fountaine, Dennis M. Callahan, Billy J. Stanbery, Harry A. Atwater, Photon and carrier management design for nonplanar thin-film copper indium gallium selenide photovoltaics, Solar Energy Materials and Solar Cells, Volume 161, March 2017, Pages 149-156, ISSN 0927-0248, (
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:72725
Deposited By: George Porter
Deposited On:12 Dec 2016 21:46
Last Modified:24 Feb 2020 22:52

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