CaltechAUTHORS
  A Caltech Library Service

A Study of the Interaction of Nitrocellulose with Some Solvents and Non-solvents by the Light-Scattering Method

Blaker, Robert H. and Badger, Richard M. (1950) A Study of the Interaction of Nitrocellulose with Some Solvents and Non-solvents by the Light-Scattering Method. Journal of the American Chemical Society, 72 (7). pp. 3129-3132. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20161216-122134178

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20161216-122134178

Abstract

A recent paper by Ewart, Roe, Debye and McCartney on the light scattering of polymers dissolved in binary mixtures suggested to us that light scattering studies should yield interesting information regarding the interaction of polymer not only with good solvents but with plasticizers which are solid or have high viscosity and indeed with non-solvents, provided both polymer and the other substance can be dissolved in a common solvent. As was shown by the above mentioned authors the addition of a third component to a polymer solvent mixture should in general cause a change in light scattering even in the absence of association, due to preferential adsorption of one or other of the solvent components by the polymer. If the solvent component adsorbed has the higher refractive index the ratio of polymer concentration to turbidity, in the limit of zero concentration, should decrease. The opposite will be true if the refractive indices are in the reverse order.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja01163a089DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01163a089PublisherArticle
Additional Information:© 1950 American Chemical Society. Received January 16, 1950.
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Gates and Crellin Laboratories of Chemistry1363
Issue or Number:7
Record Number:CaltechAUTHORS:20161216-122134178
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20161216-122134178
Official Citation:A Study of the Interaction of Nitrocellulose with Some Solvents and Non-solvents by the Light-Scattering Method Robert H. Blaker and Richard M. Badger Journal of the American Chemical Society 1950 72 (7), 3129-3132 DOI: 10.1021/ja01163a089
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:72911
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:16 Dec 2016 23:19
Last Modified:03 Oct 2019 16:22

Repository Staff Only: item control page