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The Vibrational Spectra of Tetrahydropyran and p-Dioxane

Burket, Stanley C. and Badger, Richard M. (1950) The Vibrational Spectra of Tetrahydropyran and p-Dioxane. Journal of the American Chemical Society, 72 (10). pp. 4397-4405. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20161216-122536051

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Abstract

Our major purpose in the present paper will be to identify the bands which arise from the stretching vibrations of the tetrahydropyran ring. While it is not expected that these bands will occur unshifted in sugar spectra, their identification may be expected to be of assistance in the discussion of sugar spectra. In the carbohydrates the hydrogens which are attached to carbons are predominantly tertiary and bands involving them may be expected to fall at somewhat higher frequencies than C-C or C-O stretchings (e.g., see Rasmussen), but in tetrahydropyran and p-dioxane some of the hydrogen frequencies do lie in this spectral region so that we include a brief treatment of the methylene vibrations.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja01166a018DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01166a018PublisherArticle
Additional Information:© 1950 American Chemical Society. Received January 16, 1950. This paper is based on work supported by the Bureau of Ordnance, United States Navy, and done under comtract with the Office of Naval Research, Contract N6-ori-102, Task Order VI.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)N6-ori-102, VI
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Gates and Crellin Laboratories of Chemistry1342
Issue or Number:10
Record Number:CaltechAUTHORS:20161216-122536051
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20161216-122536051
Official Citation:The Vibrational Spectra of Tetrahydropyran and p-Dioxane Stanley C. Burket and Richard M. Badger Journal of the American Chemical Society 1950 72 (10), 4397-4405 DOI: 10.1021/ja01166a018
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:72912
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:16 Dec 2016 23:25
Last Modified:03 Oct 2019 16:22

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