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Composition and structure of a (benzimidazole)chlorobis(ethylenediamine)cobalt salt

Marsh, Richard E. (1992) Composition and structure of a (benzimidazole)chlorobis(ethylenediamine)cobalt salt. Inorganic Chemistry, 31 (23). p. 4890. ISSN 0020-1669. doi:10.1021/ic00049a031. https://resolver.caltech.edu/CaltechAUTHORS:20170118-150854030

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Abstract

I wish to make a number of corrections to the description of the composition and crystal structure of a compound previously identified as "bis(ethylenediamine) (benzimidazole)chlorocobalt-(111) perchlorate". The corrections are as follows: (1) the compound is the chloride salt, rather than the perchlorate; (2) the crystals are hydrated, with the empirical formula being approximately [Co(en)_2(Cl) (benzimidazole)] Cl_2•1.3H_2O; (3) the calculateddensityis 1.56, rather than 2.94, g/cm^3; (4) thecrystals are monoclinic, space group C2/c, rather than triclinic, P1.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ic00049a031DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ic00049a031PublisherArticle
Additional Information:© 1992 American Chemical Society. Received May 8, 1992.
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Division of Chemistry and Chemical Engineering8627
Issue or Number:23
DOI:10.1021/ic00049a031
Record Number:CaltechAUTHORS:20170118-150854030
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170118-150854030
Official Citation:Composition and structure of a (benzimidazole)chlorobis(ethylenediamine)cobalt salt Richard E. Marsh Inorganic Chemistry 1992 31 (23), 4890-4890 DOI: 10.1021/ic00049a031
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:73534
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:19 Jan 2017 21:13
Last Modified:11 Nov 2021 05:18

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