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On the crystal structures of two inclusion compounds of tris(5-acetyl-3-thienyl)methane

Marsh, Richard E. (1994) On the crystal structures of two inclusion compounds of tris(5-acetyl-3-thienyl)methane. Acta crystallographica. Section B, Structural science, 50 (1). pp. 112-116. ISSN 0108-7681. https://resolver.caltech.edu/CaltechAUTHORS:20170120-155711328

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Abstract

The crystal structures of the ethanol and the ethyl acetate inclusion compounds of TATM, CH(C_6-H_5OS)_3, were originally reported in space group P1, with two independent TATM molecules and one solvent molecule in the unit cell. However, the pairs of TATM molecules are closely related by centers of symmetry and the structures are better described in space group P1. Refinements in P1 led to lower e.s.d. 's and R values and to much more reasonable bond lengths, angles and U_(ij)’s for the TATM molecules; however, the solvent molecules are disordered and can be described no better in P1 than they were in P1.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1107/S0108768193009152DOIArticle
http://scripts.iucr.org/cgi-bin/paper?S0108768193009152PublisherArticle
Additional Information:© 1994 International Union of Crystallography. Received 13 April 1993; accepted 31 August 1993.
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Other Numbering System NameOther Numbering System ID
Caltech Division of Chemistry and Chemical Engineering8771
Issue or Number:1
Record Number:CaltechAUTHORS:20170120-155711328
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170120-155711328
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:73602
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:21 Jan 2017 01:15
Last Modified:03 Oct 2019 16:29

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