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On the structure of the mixed ligand complex of [VO]^(2+) with hydrotris(3,5-dimethylpyrazolyl)borato and 1,3-diphenyl-1,3-propanedionato ligands

Marsh, Richard E. (1994) On the structure of the mixed ligand complex of [VO]^(2+) with hydrotris(3,5-dimethylpyrazolyl)borato and 1,3-diphenyl-1,3-propanedionato ligands. Acta Crystallographica Section C, 50 (10). pp. 1596-1598. ISSN 0108-2701. https://resolver.caltech.edu/CaltechAUTHORS:20170123-155317741

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Abstract

The structure of (1,3-diphenyl-1,3-propanedionato,κ^2O,O')oxo[tris(3,5-dimethyl-1-pyrazolyl-κN^2)hydroborato] vanadium(IV) methyl cyanide, [VO(C_(15)H_(22)-BN_6)(C_(15)H_(11)O_2)].xCH_3CN, has recently been described and refined [Beddoes, Eardley, Mabbs, Moorcroft & Passand (1993). Acta Cryst. C49, 1923-1926] in space group Pna2_1 (orthorhombic; a = 15.960 (1), b = 12.447 (1), c = 17.044 (1) Å, z = 4). It is better described in Pnma (conventional setting of Pnam). Revised coordinates are given and the anomalous bond lengths reported earlier are revised.


Item Type:Article
Related URLs:
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http://dx.doi.org/10.1107/S0108270194004154DOIArticle
http://scripts.iucr.org/cgi-bin/paper?S0108270194004154PublisherArticle
Additional Information:© 1994 International Union of Crystallography. Received 17 January 1994; accepted 19 April 1994.
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Caltech Division of Chemistry and Chemical Engineering8918
Issue or Number:10
Record Number:CaltechAUTHORS:20170123-155317741
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170123-155317741
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:73638
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:26 Jan 2017 20:39
Last Modified:03 Oct 2019 16:29

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