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The Development of L_2X_2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story

Trnka, Tina M. and Grubbs, Robert H. (2001) The Development of L_2X_2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story. Accounts of Chemical Research, 34 (1). pp. 18-29. ISSN 0001-4842. https://resolver.caltech.edu/CaltechAUTHORS:20170124-153104601

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Abstract

In recent years, the olefin metathesis reaction has attracted widespread attention as a versatile carbon−carbon bond-forming method. Many new applications have become possible because of major advances in catalyst design. State-of-the-art ruthenium catalysts are not only highly active but also compatible with most functional groups and easy to use. This Account traces the ideas and discoveries that were instrumental in the development of these catalysts, with particular emphasis on (PCy_3)_2Cl_2Ru═CHPh and its derivatives. The discussion includes an analysis of trends in catalyst activity, a description of catalysts coordinated with N-heterocyclic carbene ligands, and an overview of ongoing work to improve the activity, stability, and selectivity of this family of L_2X_2Ru═CHR complexes.


Item Type:Article
Related URLs:
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http://dx.doi.org/10.1021/ar000114fDOIArticle
http://pubs.acs.org/doi/full/10.1021/ar000114fPublisherArticle
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2001 American Chemical Society. Received 20 June 2000. Published online 4 November 2000. Published in print 1 January 2001. R.H.G. thanks the National Institutes of Health and the National Science Foundation for their generous support of this research.
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Issue or Number:1
Record Number:CaltechAUTHORS:20170124-153104601
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170124-153104601
Official Citation:The Development of L2X2RuCHR Olefin Metathesis Catalysts:  An Organometallic Success Story Tina M. Trnka and Robert H. Grubbs Accounts of Chemical Research 2001 34 (1), 18-29 DOI: 10.1021/ar000114f
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:73676
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:26 Jan 2017 00:25
Last Modified:03 Oct 2019 16:30

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