Severin, Erik J. and Lewis, Nathan S. (2000) Relationships among Resonant Frequency Changes on a Coated Quartz Crystal Microbalance, Thickness Changes, and Resistance Responses of Polymer−Carbon Black Composite Chemiresistors. Analytical Chemistry, 72 (9). pp. 2008-2015. ISSN 0003-2700. doi:10.1021/ac991026f. https://resolver.caltech.edu/CaltechAUTHORS:20170125-070259952
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Abstract
The relationships among frequency changes on a film-coated quartz crystal microbalance, thickness changes, and dc resistance changes have been investigated for carbon black−insulating polymer composite vapor detectors. Quartz crystal microbalance (QCM) measurements and ellipsometry measurements have been performed simultaneously on polymer films that do not contain carbon black filler to relate the QCM frequency change and the ellipsometrically determined thickness change to the analyte concentration in the vapor phase. In addition, quartz crystal microbalance measurements and dc resistance measurements on carbon black composites of these same polymers have been performed simultaneously to relate the QCM frequency change and dc electrical resistance response to the analyte concentration in the vapor phase. The data indicate that the dc resistance change is directly relatable to the thickness change of the polymers and that a variety of analytes that produce a given thickness change produce a constant resistance change for each member of the test set of polymers investigated in this work.
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Additional Information: | © 2000 American Chemical Society. Received 7 September 1999. Published online 1 April 2000. Published in print 1 May 2000. This work was supported by the National Aeronautics and Space Administration, the Army Research Office, and the Defense Advanced Research Projects Agency. | ||||||||||||
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Issue or Number: | 9 | ||||||||||||
DOI: | 10.1021/ac991026f | ||||||||||||
Record Number: | CaltechAUTHORS:20170125-070259952 | ||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170125-070259952 | ||||||||||||
Official Citation: | Relationships among Resonant Frequency Changes on a Coated Quartz Crystal Microbalance, Thickness Changes, and Resistance Responses of Polymer−Carbon Black Composite Chemiresistors Erik J. Severin and Nathan S. Lewis Analytical Chemistry 2000 72 (9), 2008-2015 DOI: 10.1021/ac991026f | ||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
ID Code: | 73688 | ||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||
Deposited By: | Ruth Sustaita | ||||||||||||
Deposited On: | 26 Jan 2017 00:11 | ||||||||||||
Last Modified: | 11 Nov 2021 05:20 |
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