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Is There Evidence for Non-Linear Thiocyanate or Selenocyanate Ions?

Marsh, Richard E. (1998) Is There Evidence for Non-Linear Thiocyanate or Selenocyanate Ions? Acta crystallographica. Section B, Structural science, 54 (4). pp. 503-504. ISSN 0108-7681. doi:10.1107/S0108768198003401.

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The structure of a mixed-valence copper complex with 1,10-phenanthroline, [Cu^(II)(phen)_2]-NC-[Cu^I(phen)((Se,S)CN)]- [(Se,S)CN].0.5(C_2H_5OH), µ-cyano-1κN:2κC-(seleno,thio)cyanato-2κN-tris(1,10-phenanthroline)-1κ^4N,N';2κ^2N,N'-dicopper(I,II) (seleno,thio)cyanate semiethanolate, has been revised from space group Cc to C2/c. Refinement in C2/c has shown that, contrary to the Cc results, the (Se,S)CN anions can be described as approximately linear, as expected.

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Additional Information:© 1998 International Union of Crystallography. Received 15 October 1997; accepted 25 February 1998.
Issue or Number:4
Record Number:CaltechAUTHORS:20170130-153025619
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:73831
Deposited By: Tony Diaz
Deposited On:30 Jan 2017 23:58
Last Modified:11 Nov 2021 05:22

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