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Revised Space Groups for Three Molybdenum(V) Phosphate Compounds

Leclaire, A. and Borel, M. M. and Guesdon, A. and Marsh, Richard E. (2001) Revised Space Groups for Three Molybdenum(V) Phosphate Compounds. Journal of Solid State Chemistry, 159 (1). pp. 7-9. ISSN 0022-4596. doi:10.1006/jssc.2001.9114.

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The space groups of three previously described Mo(V) phosphate structures are revised. (1) δ-KMo_2P_3O_(13), originally reported as triclinic, P1, is revised to monoclinic, C2/c; it is identical to the compound previously identified as K_4Mo_8P_(12)O_(52). (2) The compound formulated as [Mo_(12)CdP_8O_(50)(OH)_(12)]Cd [N(CH_3)_4]_2(H_3O)_6·5H_2O, originally described as monoclinic, Pn, is revised to P2_1/n (also monoclinic). (3) Rb_3O_2(MoO)_4(PO_4)_4, originally reported as orthorhombic, C2221, is revised to tetragonal, P4_32_12. The general descriptions of the structures are unchanged; however, for compound 2 the revision involves the addition of a center of symmetry and, as a result, there are significant changes in the interatomic distances and angles.

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Additional Information:© 2001 Academic Press. Received 22 December 2000, Accepted 19 January 2001, Available online 25 May 2002.
Issue or Number:1
Record Number:CaltechAUTHORS:20170131-082926028
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Official Citation:A. Leclaire, M.M. Borel, A. Guesdon, Richard E. Marsh, Revised Space Groups for Three Molybdenum(V) Phosphate Compounds, Journal of Solid State Chemistry, Volume 159, Issue 1, June 2001, Pages 7-9, ISSN 0022-4596, (//
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:73848
Deposited By: Tony Diaz
Deposited On:31 Jan 2017 17:49
Last Modified:11 Nov 2021 05:22

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