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Di-μ-acetato-κ^4O:O′-tetracarbonylbis(pyridyl-2-yl-κN-amine)diruthenium(I)(Ru—Ru)

Dorta, Reto and Süss-Fink, Georg and Stoeckli-Evans, Helen (2004) Di-μ-acetato-κ^4O:O′-tetracarbonylbis(pyridyl-2-yl-κN-amine)diruthenium(I)(Ru—Ru). Acta Crystallographica Section E: Structure Reports Online, 60 (10). m1397-m1399. ISSN 1600-5368. https://resolver.caltech.edu/CaltechAUTHORS:20170201-112626851

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Abstract

The structure of the title compound, [Ru_2(C_2H_3O_2)_2(C_5H_6N_2)_2(CO)_4], consists of a `sawhorse' diruthenium complex with two acetate bridges and two 2-amino­pyridine ligands in the axial positions, coordinating via the pyridine N atoms. A double-stranded hydrogen-bonded chain is formed via intra- and intermolecular hydrogen bonds involving the amine groups, one O atom of both acetate groups and two carbonyl O atoms.


Item Type:Article
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http://dx.doi.org/10.1107/S160053680402166XDOIArticle
http://journals.iucr.org/e/issues/2004/10/00/ci6437/index.htmlRelated ItemArticle
http://scripts.iucr.org/cgi-bin/paper?ci6437#suppinfoanchorRelated ItemSupporting Information
Additional Information:© 2004 International Union of Crystallography. Received 26 August 2004. Accepted 2 September 2004. Online 11 September 2004. This work was supported by the Swiss National Science Foundation.
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Swiss National Science Foundation (SNSF)UNSPECIFIED
Issue or Number:10
Record Number:CaltechAUTHORS:20170201-112626851
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170201-112626851
Official Citation: Di-μ-acetato-κ4O:O′-tetra­carbonyl­bis­(pyridyl-2-yl-κN-amine)­diruthenium(I)(Ru—Ru) R. Dorta, G. Süss-Fink and H. Stoeckli-Evans Acta Cryst. (2004). E60, m1397-m1399 doi: 10.1107/S160053680402166X
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:73936
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:01 Feb 2017 21:50
Last Modified:03 Oct 2019 16:32

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