CaltechAUTHORS
  A Caltech Library Service

Proton-Conducting Solid Electrolyte via Ozonolysis of Cationic Ammonium Organoalkoxysilane Surfactant-Templated MCM-41

Alabi, Christopher A. and Davis, Mark E. (2006) Proton-Conducting Solid Electrolyte via Ozonolysis of Cationic Ammonium Organoalkoxysilane Surfactant-Templated MCM-41. Chemistry of Materials, 18 (24). pp. 5634-5636. ISSN 0897-4756. doi:10.1021/cm061722d. https://resolver.caltech.edu/CaltechAUTHORS:20170201-141753934

[img] PDF (Proton-Conducting Solid Electrolyte via Ozonolysis...) - Supplemental Material
See Usage Policy.

116kB

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20170201-141753934

Abstract

A functional polymerizable surfactant has been synthesized and used as a template to prepare MCM-41. Ozonolysis of the olefin functional group in the composite material generates a nonporous proton-conducting solid acid that has a conductivity of ca. 6 mS cm^(-1) at 95 °C and an activation energy of 14.2 kJ/mol.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/cm061722dDOIArticle
http://pubs.acs.org/doi/full/10.1021/cm061722dPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/cm061722dRelated ItemSupporting Information
ORCID:
AuthorORCID
Alabi, Christopher A.0000-0003-2654-018X
Davis, Mark E.0000-0001-8294-1477
Additional Information:© 2006 American Chemical Society. Received 24 July 2006. Published online 31 October 2006. Published in print 28 November 2006. This research was supported by a grant from the U.S. Department of Energy for Scientific Research in the area of PEMFC.
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)UNSPECIFIED
Issue or Number:24
DOI:10.1021/cm061722d
Record Number:CaltechAUTHORS:20170201-141753934
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170201-141753934
Official Citation:Proton-Conducting Solid Electrolyte via Ozonolysis of Cationic Ammonium Organoalkoxysilane Surfactant-Templated MCM-41 Christopher A. Alabi and and Mark E. Davis* Chemistry of Materials 2006 18 (24), 5634-5636 DOI: 10.1021/cm061722d
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:73948
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:02 Feb 2017 03:35
Last Modified:11 Nov 2021 05:23

Repository Staff Only: item control page