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Epitaxial Manganese Oxide Thin Films with Connected Porosity: Topotactic Induction of Crystallographic Pore Alignment

Toberer, Eric S. and Grossman, Madeleine and Schladt, Thomas and Lange, Frederick F. and Seshadri, Ram (2007) Epitaxial Manganese Oxide Thin Films with Connected Porosity: Topotactic Induction of Crystallographic Pore Alignment. Chemistry of Materials, 19 (20). pp. 4833-4838. ISSN 0897-4756. https://resolver.caltech.edu/CaltechAUTHORS:20170203-100737307

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Abstract

Epitaxial thin films of ZnMn_2O_4, grown from an aqueous solution on (100) and (111) spinel MgAl_2O_4 substrates, have been topotactically reduced and leached to produce epitaxial rock salt MnO on the same substrates. The volume change accompanying the conversion of ZnMn_2O_4 to 2MnO associated with a loss of Zn and O_2 manifests as a network of interconnected, 50−100 nm pores. The topotactic nature of the transformation ensures that the pores are crystallographically aligned with the substrate:  on the (100) MgAl_2O_4 substrate, pores with rectangular cross-sections are aligned parallel to the surface normal. On the (111) MgAl_2O_4 substrate, the pores are aligned at constant, fixed angles with respect to the substrate normal.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/cm0714133DOIArticle
http://pubs.acs.org/doi/abs/10.1021/cm0714133PublisherArticle
Additional Information:© 2007 American Chemical Society. Received 24 May 2007. Published online 28 August 2007. Published in print 1 October 2007. We thank Adele Tamboli for helpful suggestions. E.S.T. is supported by an NSF IGERT Fellowship (DGE 9987618) and M.G. is supported by a RISE undergraduate fellowship. We gratefully acknowledge support from the donors of the American Chemical Society Petroleum Research Fund and the National Science Foundation for a Chemical Bonding Center (CHE 0434567) and for use of MRSEC facilities (DMR 0520415).
Funders:
Funding AgencyGrant Number
NSF Graduate Research FellowshipDGE-9987618
Deutscher Akademischer Austauschdienst (DAAD)UNSPECIFIED
American Chemical Society Petroleum Research FundUNSPECIFIED
NSFCHE-0434567
NSFDMR-0520415
Issue or Number:20
Record Number:CaltechAUTHORS:20170203-100737307
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170203-100737307
Official Citation:Epitaxial Manganese Oxide Thin Films with Connected Porosity:  Topotactic Induction of Crystallographic Pore Alignment Eric S. Toberer, Madeleine Grossman, Thomas Schladt, Frederick F. Lange, and Ram Seshadri Chemistry of Materials 2007 19 (20), 4833-4838 DOI: 10.1021/cm0714133
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:74016
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:03 Feb 2017 20:18
Last Modified:03 Oct 2019 16:33

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