Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations

Bhat, Vikram and Welin, Eric R. and Guo, Xuelei and Stoltz, Brian M. (2017) Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations. Chemical Reviews, 117 (5). pp. 4528-4561. ISSN 0009-2665. PMCID PMC5516946. doi:10.1021/acs.chemrev.6b00731. https://resolver.caltech.edu/CaltechAUTHORS:20170211-113501417

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Abstract

Stereoconvergent catalysis is an important subset of asymmetric synthesis that encompasses stereoablative transformations, dynamic kinetic resolutions, and dynamic kinetic asymmetric transformations. Initially, only enzymes were known to catalyze dynamic kinetic processes, but recently various synthetic catalysts have been developed. This Review summarizes major advances in nonenzymatic, transition-metal-promoted dynamic asymmetric transformations reported between 2005 and 2015.

Item Type:

Article

Related URLs:

URL	URL Type	Description
https://doi.org/10.1021/acs.chemrev.6b00731	DOI	Article
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5516946	PubMed Central	Article

ORCID:

Author	ORCID
Bhat, Vikram	0000-0001-5621-5121
Welin, Eric R.	0000-0002-1760-4121
Stoltz, Brian M.	0000-0001-9837-1528

Additional Information:

© 2017 American Chemical Society. Received: October 31, 2016; Published: February 6, 2017. This work was supported in part by the NIH-NIGMS (Grant R01GM080269), Caltech, the Gordon and Betty Moore Foundation, and the Margaret E. Early Medical Research Trust. E.R.W. was supported by a Postdoctoral Fellowship, PF-16-011-01-CDD, from the American Cancer Society. The authors declare no competing financial interest.

Funders:

Funding Agency	Grant Number
NIH	R01GM080269
Caltech	UNSPECIFIED
Gordon and Betty Moore Foundation	UNSPECIFIED
Margaret E. Early Medical Research Trust	UNSPECIFIED
American Cancer Society	PF-16-011-01-CDD

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PubMed Central ID:

PMC5516946

DOI:

10.1021/acs.chemrev.6b00731

Record Number:

CaltechAUTHORS:20170211-113501417

Persistent URL:

https://resolver.caltech.edu/CaltechAUTHORS:20170211-113501417

Official Citation:

Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations Vikram Bhat, Eric R. Welin, Xuelei Guo, and Brian M. Stoltz Chemical Reviews 2017 117 (5), 4528-4561 DOI: 10.1021/acs.chemrev.6b00731

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No commercial reproduction, distribution, display or performance rights in this work are provided.

ID Code:

74219

Collection:

CaltechAUTHORS

Deposited By:

George Porter

Deposited On:

13 Feb 2017 16:45

Last Modified:

05 Apr 2022 17:57

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