Bhat, Vikram and Welin, Eric R. and Guo, Xuelei and Stoltz, Brian M. (2017) Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations. Chemical Reviews, 117 (5). pp. 4528-4561. ISSN 0009-2665. https://resolver.caltech.edu/CaltechAUTHORS:20170211-113501417
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Abstract
Stereoconvergent catalysis is an important subset of asymmetric synthesis that encompasses stereoablative transformations, dynamic kinetic resolutions, and dynamic kinetic asymmetric transformations. Initially, only enzymes were known to catalyze dynamic kinetic processes, but recently various synthetic catalysts have been developed. This Review summarizes major advances in nonenzymatic, transition-metal-promoted dynamic asymmetric transformations reported between 2005 and 2015.
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| Additional Information: | © 2017 American Chemical Society. Received: October 31, 2016; Published: February 6, 2017. This work was supported in part by the NIH-NIGMS (Grant R01GM080269), Caltech, the Gordon and Betty Moore Foundation, and the Margaret E. Early Medical Research Trust. E.R.W. was supported by a Postdoctoral Fellowship, PF-16-011-01-CDD, from the American Cancer Society. The authors declare no competing financial interest. | ||||||||||||
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| Issue or Number: | 5 | ||||||||||||
| Record Number: | CaltechAUTHORS:20170211-113501417 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170211-113501417 | ||||||||||||
| Official Citation: | Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations Vikram Bhat, Eric R. Welin, Xuelei Guo, and Brian M. Stoltz Chemical Reviews 2017 117 (5), 4528-4561 DOI: 10.1021/acs.chemrev.6b00731 | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 74219 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | George Porter | ||||||||||||
| Deposited On: | 13 Feb 2017 16:45 | ||||||||||||
| Last Modified: | 03 Oct 2019 16:36 |
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