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Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations

Bhat, Vikram and Welin, Eric R. and Guo, Xuelei and Stoltz, Brian M. (2017) Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations. Chemical Reviews, 117 (5). pp. 4528-4561. ISSN 0009-2665. https://resolver.caltech.edu/CaltechAUTHORS:20170211-113501417

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Abstract

Stereoconvergent catalysis is an important subset of asymmetric synthesis that encompasses stereoablative transformations, dynamic kinetic resolutions, and dynamic kinetic asymmetric transformations. Initially, only enzymes were known to catalyze dynamic kinetic processes, but recently various synthetic catalysts have been developed. This Review summarizes major advances in nonenzymatic, transition-metal-promoted dynamic asymmetric transformations reported between 2005 and 2015.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/acs.chemrev.6b00731DOIArticle
http://pubs.acs.org/doi/abs/10.1021/acs.chemrev.6b00731PublisherArticle
ORCID:
AuthorORCID
Bhat, Vikram0000-0001-5621-5121
Welin, Eric R.0000-0002-1760-4121
Stoltz, Brian M.0000-0001-9837-1528
Additional Information:© 2017 American Chemical Society. Received: October 31, 2016; Published: February 6, 2017. This work was supported in part by the NIH-NIGMS (Grant R01GM080269), Caltech, the Gordon and Betty Moore Foundation, and the Margaret E. Early Medical Research Trust. E.R.W. was supported by a Postdoctoral Fellowship, PF-16-011-01-CDD, from the American Cancer Society. The authors declare no competing financial interest.
Funders:
Funding AgencyGrant Number
NIHR01GM080269
CaltechUNSPECIFIED
Gordon and Betty Moore FoundationUNSPECIFIED
Margaret E. Early Medical Research TrustUNSPECIFIED
American Cancer SocietyPF-16-011-01-CDD
Issue or Number:5
Record Number:CaltechAUTHORS:20170211-113501417
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170211-113501417
Official Citation:Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations Vikram Bhat, Eric R. Welin, Xuelei Guo, and Brian M. Stoltz Chemical Reviews 2017 117 (5), 4528-4561 DOI: 10.1021/acs.chemrev.6b00731
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:74219
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:13 Feb 2017 16:45
Last Modified:03 Oct 2019 16:36

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