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Enantioselective Tsuji Allylations

Mohr, Justin T. and Stoltz, Brian M. (2007) Enantioselective Tsuji Allylations. Chemistry – An Asian Journal, 2 (12). pp. 1476-1491. ISSN 1861-4728. PMCID PMC2967289. https://resolver.caltech.edu/CaltechAUTHORS:20170215-130857215

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Abstract

The family of allylation reactions developed by Tsuji in the 1980s are capable of generating tertiary and quaternary carbon stereocenters from several synthetic precursors. Despite the utility of these transformations, they have seen little use in the synthesis of natural products. Recently, the power of these reactions was significantly enhanced by the development of enantioselective versions of these transformations. Applications of these methods to the enantioselective syntheses of natural products and pharmaceutical compounds highlight the importance of these developments.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://dx.doi.org/10.1002%2Fasia.200700183DOIArticle
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967289/PubMed CentralArticle
ORCID:
AuthorORCID
Mohr, Justin T.0000-0002-7005-3322
Stoltz, Brian M.0000-0001-9837-1528
Additional Information:© 2007 John Wiley & Sons, Inc. Manuscript Received: 31 May 2007. Version of record online: 12 October 2007. Issue online: 27 November 2007. We dedicate this focus review to Prof. Jiro Tsuji on the occasion of his 80th birthday. We thank Eli Lilly (predoctoral fellowship to JTM) and Caltech for financial support, Douglas C. Behenna for helpful conversations, and Masaki Seto for translating the abstract into Japanese. We thank NIH-NIGMS (R01 GM 080269-01), Eli Lilly (predoctoral fellowship to J.T.M.), and Caltech for financial support, Douglas C. Behenna for helpful conversations, and Masaki Seto for translating the abstract into Japanese.
Funders:
Funding AgencyGrant Number
NIHR01GM080269-01
Eli LillyUNSPECIFIED
CaltechUNSPECIFIED
Subject Keywords:allylation; asymmetric catalysis; enols; ketones; palladium
Issue or Number:12
PubMed Central ID:PMC2967289
Record Number:CaltechAUTHORS:20170215-130857215
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170215-130857215
Official Citation:Mohr, Justin T. and Stoltz, Brian M. (2007), Enantioselective Tsuji Allylations. Chem. Asian J., 2: 1476–1491. doi:10.1002/asia.200700183
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:74327
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:15 Feb 2017 21:49
Last Modified:15 Jun 2020 20:00

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