Mohr, Justin T. and Stoltz, Brian M. (2007) Enantioselective Tsuji Allylations. Chemistry – An Asian Journal, 2 (12). pp. 1476-1491. ISSN 1861-4728. PMCID PMC2967289. https://resolver.caltech.edu/CaltechAUTHORS:20170215-130857215
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Abstract
The family of allylation reactions developed by Tsuji in the 1980s are capable of generating tertiary and quaternary carbon stereocenters from several synthetic precursors. Despite the utility of these transformations, they have seen little use in the synthesis of natural products. Recently, the power of these reactions was significantly enhanced by the development of enantioselective versions of these transformations. Applications of these methods to the enantioselective syntheses of natural products and pharmaceutical compounds highlight the importance of these developments.
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| Additional Information: | © 2007 John Wiley & Sons, Inc. Manuscript Received: 31 May 2007. Version of record online: 12 October 2007. Issue online: 27 November 2007. We dedicate this focus review to Prof. Jiro Tsuji on the occasion of his 80th birthday. We thank Eli Lilly (predoctoral fellowship to JTM) and Caltech for financial support, Douglas C. Behenna for helpful conversations, and Masaki Seto for translating the abstract into Japanese. We thank NIH-NIGMS (R01 GM 080269-01), Eli Lilly (predoctoral fellowship to J.T.M.), and Caltech for financial support, Douglas C. Behenna for helpful conversations, and Masaki Seto for translating the abstract into Japanese. | |||||||||
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| Subject Keywords: | allylation; asymmetric catalysis; enols; ketones; palladium | |||||||||
| Issue or Number: | 12 | |||||||||
| PubMed Central ID: | PMC2967289 | |||||||||
| Record Number: | CaltechAUTHORS:20170215-130857215 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170215-130857215 | |||||||||
| Official Citation: | Mohr, Justin T. and Stoltz, Brian M. (2007), Enantioselective Tsuji Allylations. Chem. Asian J., 2: 1476–1491. doi:10.1002/asia.200700183 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 74327 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 15 Feb 2017 21:49 | |||||||||
| Last Modified: | 15 Jun 2020 20:00 |
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