CaltechAUTHORS
  A Caltech Library Service

Palladium-Catalyzed Oxidative Kinetic Resolution with Ambient Air as the Stoichiometric Oxidation Gas

Bagdanoff, Jeffrey T. and Stoltz, Brian M. (2004) Palladium-Catalyzed Oxidative Kinetic Resolution with Ambient Air as the Stoichiometric Oxidation Gas. Angewandte Chemie International Edition, 43 (3). pp. 353-357. ISSN 1433-7851. doi:10.1002/anie.200352444. https://resolver.caltech.edu/CaltechAUTHORS:20170215-145714988

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20170215-145714988

Abstract

Air is enough to mediate the highly enantioselective oxidation of secondary alcohols at room temperature with palladium(II) and sparteine in nonflammable solvents. Examination of the role of solvents capable of hydrogen bonding and their ability to solvate halide anions led to a novel set of conditions for the highly enantioselective oxidative kinetic resolution of secondary alcohols.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/anie.200352444DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/anie.200352444/abstractPublisherArticle
ORCID:
AuthorORCID
Stoltz, Brian M.0000-0001-9837-1528
Additional Information:© 2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Issue online: 29 December 2003; Version of record online: 29 December 2003; Manuscript Received: 22 July 2003. The authors thank the NIH-NIGMS (R01 GM65961-01), the University of California TRDRP (predoctoral fellowship to JTB), the Dreyfus Foundation, Merck Research Laboratories, Research Corporation, Abbott Laboratories, Eli Lilly, GlaxoSmithKline, Johnson and Johnson, Pfizer, and the A. P. Sloan Foundation for generous financial support.
Funders:
Funding AgencyGrant Number
NIHR01GM65961-01
California Tobacco-Related Disease Research ProgramUNSPECIFIED
Camille and Henry Dreyfus FoundationUNSPECIFIED
Merck Research LaboratoriesUNSPECIFIED
Research CorporationUNSPECIFIED
Abbott LaboratoriesUNSPECIFIED
Eli LillyUNSPECIFIED
GlaxoSmithKlineUNSPECIFIED
Johnson and JohnsonUNSPECIFIED
PfizerUNSPECIFIED
Alfred P. Sloan FoundationUNSPECIFIED
Subject Keywords:asymmetric catalysis; hydrogen bonds; oxidation; oxygen; palladium; solvent effects
Issue or Number:3
DOI:10.1002/anie.200352444
Record Number:CaltechAUTHORS:20170215-145714988
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170215-145714988
Official Citation:Bagdanoff, J. T. and Stoltz, B. M. (2004), Palladium-Catalyzed Oxidative Kinetic Resolution with Ambient Air as the Stoichiometric Oxidation Gas. Angewandte Chemie International Edition, 43: 353–357. doi:10.1002/anie.200352444
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:74337
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:15 Feb 2017 23:21
Last Modified:11 Nov 2021 05:26

Repository Staff Only: item control page